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Effects of nano calcium carbonate on the properties of frontal-polymerized dicyclopentadiene resin
LI Kehui, ZHANG Yueyao, SONG Longjie, YANG Liling, CHEN Dingding, XING Suli, YIN Changping, TANG Jun
COMPOSITES SCIENCE AND ENGINEERING
2025, 0 (9):
35-41.
DOI: 10.19936/j.cnki.2096-8000.20250928.005
This study was systematically conducted to investigate the effects of nano-CaCO
3 modification on the processing, thermal stability, and mechanical properties of frontal-polymerized dicyclopentadiene (DCPD) resin. The results demonstrate that the incorporation of nano-CaCO
3 significantly optimized the processing window of DCPD resin. Thus, the initial curing temperature and peak curing temperature are decreased by 16.16 ℃ and 13.92 ℃, respectively, while the room-temperature gelation time extends beyond 2.5 h. Furthermore, as nano-CaCO
3 suppressed the mobility of molecular chain, the glass transition temperature (
T
g) is elevated to 127.9 ℃, which is a 33.79% increase over that of the pure resin. Mechanically, the flexural strength, tensile modulus, and impact strength are improved to 60.53 MPa, 1.90 GPa and 4.84 kJ/m
2 with the optimal nano-CaCO
3 content (3wt%~4wt%), representing improvements of 13.27%, 57.02% and 9.09%, respectively. However, due to the stress concentration caused by the agglomeration of nano-CaCO
3 particles at high content (>5wt%), the mechanical properties of the DCPD resin are degraded. This work could provide insights for designing high-performance frontal-polymerized polymer composites with tailored processability and thermal-mechanical properties.
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