高性能环氧树脂改性胶黏剂研究进展

doi:10.19936/j.cnki.2096-8000.20260628.018

摘要/Abstract

摘要： 随着现代工业技术发展对材料性能要求的提升,航空制造领域亟需通过持续优化环氧胶黏剂在复杂工况下的综合性能,突破飞机蜂窝夹层结构粘接与密封关键技术,以推动我国航空工业轻量化与可靠性协同创新。本文综述了环氧树脂改性胶黏剂的实际应用及研究进展,介绍了其耐温性的技术方法,分析了环氧胶黏剂的耐温性能影响因素,阐释了环氧胶强韧化机理。

关键词: 环氧树脂, 胶黏剂, 耐高温, 增韧

Abstract: With the development of modern industrial technology, the requirements for material performance are continuously increasing. The aviation manufacturing sector urgently needs to continuously optimize the comprehensive performance of epoxy adhesives under complex working conditions, to overcome the key technologies of bonding and sealing in aircraft honeycomb sandwich structures, thereby promoting the collaborative innovation of lightweight and reliability in China’s aviation industry. This paper reviews the practical applications and research progress of epoxy resin adhesives, emphasizing the influencing factors of the thermal resistance performance of epoxy adhesives and the technical methods to improve their thermal resistance, as well as providing a detailed explanation of the toughening mechanism of epoxy resins.

Key words: epoxy resin, adhesive, high temperature resistance, toughening

中图分类号:

TB332

赵岩, 穆雪松, 陈文刚. 高性能环氧树脂改性胶黏剂研究进展[J]. 复合材料科学与工程, 2026, 0(6): 159-168.

ZHAO Yan, MU Xuesong, CHEN Wengang. Research advances in high performance epoxy resin adhesives[J]. COMPOSITES SCIENCE AND ENGINEERING, 2026, 0(6): 159-168.

参考文献

[1] LI H, LUO Y S, HU D L, et al. Effect of hydrothermal aging on the dynamic mechanical performance of the room temperature-cured epoxy adhesive[J]. Rheologica Acta, 2019, 58(1):9-19.
[2] BRUCKNER T M, SINGEWALD T D, GRUBER R, et al. Water absorption and leaching of a 1K structural model epoxy adhesive for the automotive industry[J]. Polymer Testing, 2023, 117:107870.
[3] HARICH N, PRIDDY M W, LACY T E, et al. Effects of cyclic absorption-desorption of model fuels by aerospace-grade carbon/epoxy composites[J]. Polymer Composites,2023, 44(8):5018-5028.
[4] BACK J H, HWANG J U, LEE Y H, et al. Morphological study and mechanical property of epoxy-foam adhesives based on epoxy composites for automotive applications[J]. International Journal of Adhesion and Adhesives, 2018, 87:124-129.
[5] SUN Z Y, LIU Y, MIN W, et al. Effect of expansion rate on interfacial mechanical properties and failure mechanism of sandwich composites prepared via thermal expansion molding process[J]. Engineering Failure Analysis, 2024, 161:108246.
[6] 高岩磊, 崔文广, 牟微, 等. 环氧树脂粘合剂热氧老化行为研究[J]. 化工新型材料, 2011, 39(2):72-74.
[7] 康瑞兴, 王鑫, 赵雄燕. 高性能环氧树脂粘合剂的改性方法及结构与性能的关系[J]. 应用化工, 2020, 49(1):230-233.
[8] ZHAO L W, LI H F, QIAO Y J, et al. Accelerated-curing epoxy structural film adhesive for bonding lightweight honeycomb sandwich structures[J]. Journal of Applied Polymer Science, 2023, 140(6):e53458.
[9] SEVERIJNS C, DE FREITAS S T, POULIS J A. Susceptor-assisted induction curing behaviour of a two component epoxy paste adhesive for aerospace applications[J]. International Journal of Adhesion and Adhesives, 2017, 75:155-164.
[10] MIN W, TAO L, YAN Z, et al. Feasibility verification and bending property of web-reinforced foam sandwich composites prepared via thermal expansion molding process[J]. Composite Structures, 2022, 294:115720.
[11] 蔡永源, 李彤, 孔莹, 等. 环氧树脂胶粘剂应用进展[J]. 化工新型材料, 2005, 33(11):17-20.
[12] 周建文. 单组分环氧树脂胶粘剂的研究现状[J]. 化学与粘合, 2004, 26(1):36-40.
[13] ZHANG J X, LIU Y, CHENG L L, et al. Design and performance study of carbon fiber-reinforced polymer connection structures with surface treatment on aluminum alloy(6061)[J]. Coatings, 2024, 14(7):785.
[14] 李娟, 郭杰, 刘青. 环氧树脂固化剂研究新进展[J]. 化工新型材料, 2017, 45(3):31-33.
[15] 唐晓东, 姚美君, 李晶晶, 等. 环氧树脂固化剂的研究新进展[J]. 塑料工业, 2023, 51(9):30-38, 52.
[16] SCHNEIDER J P, LENGSFELD H. Toughening of a dicyandiamide-cured epoxy resin:influence of cure conditions on different rubber modifications[J]. Polymer Engineering & Science,2021, 61(10):2445-2452.
[17] ALBUQUERQUE A K C, ALMEIDA D E O, BARRETO J V M, et al. Effect of hardener and catalyst contents on curing and degradation of epoxidized soybean oil[J]. Journal of Applied Polymer Science, 2023, 140(3):e53343.
[18] ZHOU W, XIA Y, TSAI F C, et al. Effects of compound curing agent on the thermo-mechanical properties and structure of epoxy asphalt[J]. International Journal of Pavement Engineering, 2017, 18(10):928-936.
[19] CONG P L, LUO W H, XU P J, et al. Chemical and physical properties of hot mixing epoxy asphalt binders[J]. Construction and Building Materials, 2019, 198:1-9.
[20] MORA A S, TAYOUO R, BOUTEVIN B, et al. A perspectiveapproach on the amine reactivity and the hydrogen bonds effect onepoxy-amine systems[J]. European Polymer Journal, 2020, 123:109460.
[21] YAMASAKI H, MORITA S. Identification of the epoxy curing mechanism under isothermal conditions by thermal analysis and infrared spectroscopy[J]. Journal of Molecular Structure, 2014, 1069:164-170.
[22] ZHOU D H, LIANG R, KANG Y. A review of chemo-rheological and thermo-rheological investigations on epoxy asphalt cementitious materials[J]. Construction and Building Materials, 2023, 395:132309.
[23] HARRIS J J, TEMIN S C. Proposed mechanism for the curing of epoxy resins with amine-lewis acid complexes or salts[J]. Journal of Applied Polymer Science, 1966, 10(4):523-534.
[24] 陈平, 张岩. 硼胺络合物/环氧树脂体系的固化反应机理及其动力学[J]. 复合材料学报, 1999, 16(4):54-57.
[25] 高玉斌, 刘述梅, 赵建青, 等. 二甲氨基乙氧基氧杂硼烷对环氧树脂的潜伏固化活性[J]. 高等学校化学学报, 2014, 35(2):396-401.
[26] QIAN Z D, CHEN L L, WANG Y Q, et al. Curing reaction model of epoxy asphalt binder[J]. Journal of Wuhan University of Technology-Materils Science Edition, 2012, 27(4):763-767.
[27] LI X H, LIU L L, YU J, et al. Full recovery of epoxy resin wastes into bisphenol A and epoxy monomers via lewis acid[J]. Angewandte Chemie International Edition, 2025, 64(19):e202422472.
[28] 罗忠文, 虞鑫海, 陈戚, 等. 双马来酰亚胺改性环氧胶粘剂的研制[J]. 粘接, 2015, 36(12):56-59.
[29] MUSA A, ALAMRY K A, HUSSEIN M A. The effect of curing temperatures on the thermal behaviour of new polybenzoxazine-modified epoxy resin[J]. Polymer Bulletin, 2020, 77(10):5439-5449.
[30] 王路平, 徐志财, 雷学成, 等. 有机硅环氧树脂的制备及其性能研究[J]. 粘接, 2016, 37(2):33-35, 32, 39.
[31] 钟元伟, 彭锦雯, 覃洁, 等. 耐高温双酚芴改性有机硅环氧树脂的合成与表征[J]. 高分子材料科学与工程, 2014, 30(1):26-30.
[32] MORITA Y, TAJIMA S, SUZUKI H, et al. Thermally initiated cationic polymerization and properties of epoxy siloxane[J]. Journal of Applied Polymer Science, 2006, 100(3):2010-2019.
[33] 李珺鹏, 齐暑华, 齐海元, 等. 聚砜改性环氧树脂复合材料热老化性能研究[J]. 中国胶粘剂, 2011, 20(2):22-25.
[34] 杨延风, 张学军. 氰酸酯树脂与环氧树脂共聚物的性能研究[J]. 化工新型材料, 2014, 42(12):183-184, 188.
[35] 杨满红, 张教强, 季铁正, 等. 氰酸酯环氧双马来酰亚胺基胶粘剂的苯并噁嗪改性研究[J]. 中国胶粘剂, 2011, 20(11):34-37.
[36] 井丰喜, 石兆从, 张道洪. 超支化聚酯改性环氧-酸酐浇注树脂及性能研究[J]. 粘接, 2016, 37(2):36-39.
[37] 王永超, 林树东, 涂园园, 等. 一种环氧树脂潜伏性固化剂二苯基双胍的合成与性能[J]. 精细化工, 2016, 33(2):224-230.
[38] ZHANG X H, CHEN S, MIN Y Q, et al. Synthesis of novel bisphenol containing phthalazinone and azomethine moieties and thermal properties of cured diamine/bisphenol/DGEBA polymers[J]. Polymer, 2006, 47(6):1785-1795.
[39] 王红凯, 李华, 李明雪, 等. 增韧耐温改性环氧树脂的制备及其表征[J]. 郑州大学学报(工学版), 2015, 36(4):28-32.
[40] 陈宇飞, 张旭, 孙佳林, 等. 二氧化钛改性环氧树脂胶黏剂的性能[J]. 江苏大学学报(自然科学版), 2013, 34(3):335-339.
[41] HESAMI M, BAGHERI R, MASOOMI M. Combination effects of carbon nanotubes, MMT and phosphorus flame retardant on fire and thermal resistance of fiber-reinforced epoxy composites[J]. Iranian Polymer Journal, 2014, 23(6):469-476.
[42] 马传国, 于英俊, 张鹏. 碳纳米管的表面修饰及其对环氧树脂热性能的影响[J]. 中国塑料, 2009, 23(1):18-23.
[43] KIM B C, PARK S W, LEE D G. Fracture toughness of the nano-particle reinforced epoxy composite[J]. Composite Structures, 2008, 86(1/2/3):69-77.
[44] KUNZ-DOUGLASS S, BEAUMONT P W R, ASHBY M F, et al. A model for the toughness of epoxy-rubber particulate composites[J]. Journal of Materials Science, 1980, 15(5):1109-1123.
[45] 沈威, 王小萍, 贾德民. 环氧树脂增韧改性技术研究进展[J]. 热固性树脂, 2010, 25(3):49-54.
[46] 胡少坤. 环氧树脂增韧改性方法研究进展[J]. 粘接, 2008, 35(6):34-37, 51.
[47] DONASCIMENTO C R F, SILVA A A, SOARES B G. Epoxy networks modified with functionalized liquid polyisoprene rubbers with enhanced toughness and stiffness[J]. Journal of Thermal Analysis and Calorimetry, 2023, 148(1):69-77.
[48] JANUSZEWSKI R, DUTKIEWICZ M, NOWICKI M, et al. Synthesis and properties of epoxy resin modified with novel reactive liquid rubber-based systems[J]. Industrial & Engineering Chemistry Research, 2021, 60(5):2178-2186.
[49] TRIPATHI G, SRIVASTAVA D. Effect of carboxyl-terminated poly(butadiene-co-acrylonitrile)(CTBN) concentration on thermal and mechanical properties of binary blends of diglycidyl ether of bisphenol-A(DGEBA) epoxy resin[J]. Materials Science and Engineering:A, 2007, 443(1/2):262-269.
[50] CHIKHI N, FELLAHI S, BAKAR M. Modification of epoxy resin using reactive liquid(ATBN) rubber[J]. European Polymer Journal, 2002, 38(2):251-264.
[51] GIANNOTTI M I, GALANTE M J, OYANGUREN P A, et al. Role of intrinsic flaws upon flexural behaviour of athermoplastic modified epoxy resin[J]. Polymer Testing, 2003, 22(4):429-437.
[52] BENNETT G S, FARRIS R J, THOMPSON S A. Amine-terminated poly(aryl ether ketone)-epoxy/amine resin systems as toughhigh-performance materials[J]. Polymer, 1991, 32(9):1633-1641.
[53] MIMURA K, ITO H, FUJIOKA H. Improvement of thermal and mechanical properties by control of morphologies in PES-modified epoxy resins[J]. Polymer, 2000, 41(12):4451-4459.
[54] 李朝阳, 邱大健, 谢国先, 等. 纳米SiO₂增韧改性环氧树脂的研究[J]. 材料保护, 2008, 41(4):21-23, 2.
[55] WANG D L, ZHANG F L, HUANG K, et al.Study on preparation and performance of advanced nano-modified epoxy asphalt[J]. Journal of Applied Polymer Science, 2023, 140(14):e53688.
[56] CHEN C G, JUSTICE R S, SCHAEFER D W, et al. Highly dispersed nanosilica-epoxy resins with enhanced mechanical properties[J]. Polymer, 2008, 49(17):3805-3815.