轻质低介电石英纤维/环氧树脂基复合材料的制备与性能

doi:10.19936/j.cnki.2096-8000.20260828.010

摘要/Abstract

摘要： 针对航空航天领域低导热及低介电性能需求,开发了一种轻质低介电石英纤维/环氧树脂基复合材料。通过差示扫描量热仪(Differential Scanning Calorimetry,DSC)及热失重分析仪(Thermogravimetric Analysis,TGA)对其热行为进行测定,采用固体密度计、导热系数测试仪及矢量网络分析仪探究其密度、导热系数和介电常数。结果表明,固化剂用量对环氧树脂交联反应效率具有显著影响。当固化剂用量为45%(以环氧树脂质量为基准)时,交联反应效率最高,固化反应热焓值最佳。当发泡剂用量为5%时,制备的石英纤维/环氧树脂基复合材料相比于未发泡的环氧树脂复合材料,密度降低27%,导热系数降低11%,介电常数降低31%,介电损耗降低48%。

关键词: 石英纤维, 环氧树脂, AC发泡剂, 介电性能, 导热系数

Abstract: A lightweight and low dielectric quartz fiber/epoxy resin based composite material has been developed to meet the requirements of low thermal conductivity and low dielectric performance in the aerospace industry. The thermal behavior of the material was determined by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). Its density, thermal conductivity and dielectric constant were investigated using a solid density meter, thermal conductivity tester and vector network analyzer. The results show that the amount of curing agent has a significant impact on the crosslinking reaction efficiency of epoxy resin. The crosslinking reaction efficiency is the highest and the curing exothermic enthalpy value is the best when the amount of curing agent is 45%(based on the mass of epoxy resin). When the amount of foaming agent is 5%, the density of the prepared quartz fiber/epoxy resin composite material is reduced by 27% compared with the unfrothed epoxy resin composite material, the thermal conductivity is reduced by 11%, the dielectric constant is reduced by 31%, and the dielectric loss is reduced by 48%.

Key words: quartz fiber, epoxy resin, AC foaming agent, dielectric properties, thermal conductivity

中图分类号:

TB332

高畅, 栾贻浩, 宋立, 邵明哲, 李洁, 王俊涛, 卢逸林, 刘战硕. 轻质低介电石英纤维/环氧树脂基复合材料的制备与性能[J]. 复合材料科学与工程, 2026, 0(8): 79-87.

GAO Chang, LUAN Yihao, SONG Li, SHAO Mingzhe, LI Jie, WANG Juntao, LU Yilin, LIU Zhanshuo. Preparation and properties of lightweight low dielectric quartz fiber/epoxy resin composites[J]. COMPOSITES SCIENCE AND ENGINEERING, 2026, 0(8): 79-87.

参考文献

[1] 石毓锬, 梁国正, 兰立文. 树脂基复合材料在导弹雷达天线罩中的应用[J]. 材料工程, 2000, 28(5): 36-39.
Shi Yutan, Liang Guozheng, Lan Liwen. Research of polymer-matrix composites for missile radomes[J]. Journal of Materials Engineering, 2000, 28(5): 36-39.
[2] Zhao Kai, Cheng Laifei, Ye Fang, et al. Preparation and performance of Si₃N₄ hollow microspheres by the template method and carbothermal reduction nitridation[J]. ACS Applied Materials & Interfaces, 2019, 11(42): 39054-39061.
[3] 陈平, 王德中. 环氧树脂及其应用[M]. 北京: 化学工业出版社, 2004.
Chen Ping, Wang Dezhong. Epoxy resin and its application[M]. Beijing: Chemical Industry Press, 2004.
[4] Wang Yuanqiang, Sun Jing, Jin Kaikai, et al. Benzocyclobutene resin with fluorene backbone: a novel thermosetting material with high thermostability and low dielectric constant[J]. RSC Advances, 2014, 4(75): 39884-39888.
[5] Kim S, Wang Xingyuan, Ando S, et al. Low dielectric and thermally stable hybrid ternary composites of hyperbranched and linearpolyimides with SiO₂[J]. RSC Advances, 2014, 4(52): 27267-27276.
[6] Kumar R S, Ariraman M, Alagar M. Design of lamellar structured POSS/BPZ polybenzoxazine nanocomposites as a novel class of ultralow-k dielectric materials[J]. RSC Advances, 2014, 4(37): 19127-19136.
[7] Park J M, Kim K H, Cheng Jin’an, et al. Highly robust SiCOH/mesoporous SiO₂ ultralow dielectric films with heterostructures[J]. RSC Advances, 2014, 4(54): 28409-28416.
[8] Luo Lijuan, Qiu Teng, Meng Yan, et al. A novel fluoro-terminated hyperbranched poly(phenylene oxide)(FHPPO): synthesis, characterization, and application in low-k epoxy materials[J]. RSC Advances, 2013, 3(34): 14509.
[9] Kumar R S, Alagar M. Dielectric and thermal behaviors of POSS reinforced polyurethane based polybenzoxazine nanocomposites[J]. RSC Advances, 2015, 5(42): 33008-33015.
[10] Zhao Xiongyan, Liu Hongjie. Review of polymer materials with low dielectric constant[J]. Polymer International, 2010, 59(5): 597-606.
[11] Tao Zhiqiang, Yang Shiyong, Ge Ziyi, et al. Synthesis and properties of novel fluorinated epoxy resins based on 1,1-bis(4-glycidylesterphenyl)-1-(3′-trifluoromethylphenyl)-2,2,2-trifluoroethane[J]. European Polymer Journal, 2007, 43(2): 550-560.
[12] Jiao Jian, Wang Lei, Lv Panpan, et al. Improved dielectric and mechanical properties of silica/epoxy resin nanocomposites prepared with a novel organic-inorganic hybrid mesoporous silica: POSS-MPS[J]. Materials Letters, 2014, 129: 16-19.
[13] 吴雄芳, 冯登柱,程章洁. 一种中温固化的高透波环氧改性氰酸酯树脂体系预浸料的制作方法: CN 201810044037.2[P]. 2018-07-13.
Wu Xiongfang,Feng Dengzhu, Cheng Zhangjie. Preparation method of medium-temperature-cured high-wave transmissvity epoxy modified cyanate resin system prepreg: CN201810044037.2[P]. 2018-07-13.
[14] 鹿海军, 邢丽英, 张宝艳. 热固性环氧泡沫材料的研究进展[J]. 材料导报, 2009, 23(23): 14-20.
Lu Haijun, Xing Liying, Zhang Baoyan. Research progress in thermoset epoxy foam composites[J]. Materials Reports, 2009, 23(23): 14-20.
[15] Gu Ruijun, Sain M, Konar S. Development and characterization of flexible epoxy foam with reactive liquid rubber and starch[J]. Journal of Materials Science, 2014, 49(8): 3125-3134.
[16] 陈卓, 黄志雄, 秦岩, 等. 空心微球/环氧树脂复合泡沫塑料的抗压性能与破坏机制[J]. 复合材料学报, 2013, 30(2): 31-36.
Chen Zhuo, Huang Zhixiong, Qin Yan, et al. Compressive property of hollow glass microsphere/epoxy resin syntactic foam and its fracture mechanism[J]. Acta Materiae Compositae Sinica, 2013, 30(2): 31-36.
[17] 刘贺, 卢都友, 陈捷, 等. 物理发泡法制备结构-保温一体化碱激发多孔材料[J]. 新型建筑材料, 2017, 44(9): 118-121.
Liu He, Lu Duyou, Chen Jie, et al. Preparation of structure thermal insulation integrated alkali-activated porous materials by physical foaming method[J]. New Building Materials, 2017, 44(9): 118-121.
[18] 范晓龙, 张广成, 李建通, 等. 环氧树脂微孔材料的制备与性能[J]. 复合材料学报, 2016, 33(9): 1915-1921.
Fan Xiaolong, Zhang Guangcheng, Li Jiantong, et al. Preparation and properties of microcellular epoxy resin[J]. Acta Materiae Compositae Sinica, 2016, 33(9): 1915-1921.
[19] 天津市合成材料工业研究所. 环氧树脂与环氧化物[M]. 天津: 天津人民出版社, 1974.
Tianjin Institute of Synthetic Materials Industry.Epoxy resin and epoxide[M]. Tianjin: Tianjin People’s Publishing House, 1974.
[20] 胡玉明. 环氧固化剂及添加剂[M]. 北京: 化学工业出版社, 2011.
Hu Yuming. Epoxy curing agent and additives[M]. Beijing: Chemical Industry Press, 2011.
[21] 陈祖敏, 栾晓明, 吕建梅, 等. AC发泡剂在PVC中应用技术[J]. 塑料助剂, 1998(2): 21-23.
Chen Zumin, Luan Xiaoming, Lü Jianmei, et al. Application technology of AC foaming agent in PVC[J]. Plastics Additives, 1998(2): 21-23.
[22] 王晓东, 花蕾, 董爱娟, 等. 基于热失重分析对聚合物发泡剂ADC发气量测定方法的研究[J]. 中国塑料, 2022, 36(1): 142-147.
Wang Xiaodong, Hua Lei, Dong Aijuan, et al. Study on measurement method of gas evolution of foaming agent ADC based onthermogravimetric analysis[J]. China Plastics, 2022, 36(1): 142-147.
[23] 周雪颖, 秦盟盟, 封伟. 优化填料结构增强聚合物基复合材料的导热性能[J]. 功能高分子学报, 2024, 37(4): 295-303.
Zhou Xueying, Qin Mengmeng, Feng Wei. Enhancing thermal conductivity of polymer matrix composite by optimizing fillerstructure[J]. Journal of Functional Polymers, 2024, 37(4): 295-303.
[24] 邢丽英. 高性能微波辐射调控复合材料技术[M]. 北京: 科学出版社, 2020.
Xing Liying. High performance microwave radiation control composite technology[M]. Beijing: Science Press, 2020.
[25] 高瑞杰, 齐磊, 郭瑞琪, 等. 纤维增强树脂基复合材料成型工艺在线监测方法研究进展[J]. 复合材料科学与工程, 2024(12): 134-146.
Gao Ruijie, Qi Lei, Guo Ruiqi, et al. Research advances in online-monitoring methods of manufacturing process for fiber reinforced resin matrix composites[J]. Composites Science and Engineering, 2024(12): 134-146.