The unsaturated polyester resin reinforced ①hemp fiber composites were formed by compression molding process, the thermooxidative aging test was carried out for 600h at 105℃. The mechanical properties of different composites before and after aging were studied, and the changes of the structures of different materials through the aging test were investigated by FTIR technology, the morphologies of the fractured surfaces of some composites were observed by SEM.The resultshows, treating the hemp fiber with silane coupling agent KH570 has the best comprehensive positive effect.The tensile strength, tensile modulus, flexural strength, flexural modulus and impact strength of the KH570 treated composite are correspondingly 19.06MPa, 5.78GPa, 52.988MPa, 1.01GPa and 3.881kJ/m2 after aging for 600 hours,which indicate that the composite still has the best mechanical properties.The FTIR spectra of the KH570 treated composite are almost the same before and after the test, and some absorbances are even strengthened. SEM pictures show that the fibers still dissipate in the matrix of the KH570 treated composite homogeneously after aging for 600 hours.