PREPARATION AND ANALYSIS OF NEW BENZOXAZINE RESIN WITH 
ETHYNYL AND ALLYL GROUP

Abstract

Abstract:

Benzoxazine with allyl group and alkyne group prepared by using 3ethynylaniline, diallylbisphenol A and formaldehyde in 1,4dioxane was synthesized, and characterized by 1H NMR and FTIR in this paper. The benzoxazine compound is liquid in room temperature. Dynamic mechanical analysis (DMA) was used for analyzing the cured product of benzoxazine compound. The results show that the cured product of benzoxazine compound has higher application temperature, its glass transition temperature can reach 367.61℃. Therefore,it could be used as a resin matrix of high performance composite.

Key words: benzoxazine, synthesis, characterization

ZHANG Ying-Jiang, XU Wei, WU Hai-Xia, MEI Li-Wen. PREPARATION AND ANALYSIS OF NEW BENZOXAZINE RESIN WITH
ETHYNYL AND ALLYL GROUP[J]. Fiber Reinforced Plastics/Composites, 2009, 209(5): 69-71.

References

［1］ Agag T, Tarek A, Tsutomu T. Synthesis and Characterization of novel benzoxazine monomers containing allyl groups and their high performance thermosets［J］. Macromolecules, 2003, 36: 60106017.
［2］ Ishida H. Physical and mechanical characterization of nearzero shrinkage po1ybenzoxazines［J］. J. Polym. Sci. Part B.,1996, 34:10191030.
［3］ Schreiber H，Sawr W．Phenolic Materials Viaringopening Polymerization of Benzoxazines: Effect of Molecular Structure on Mechanical and Dynamic Mechanical Properties［J］. Macromal. Chem., 1993, 74:l65171
［4］朱国敏，沈学宁，黄发荣．二乙烯基硅氧烷双苯并环丁烯树脂的制备与性能研究［J］. 玻璃钢/ 复合材料, 2005, (4):1619.
［5］虞莲雯, 王耀先, 陈兴旺.改性双马来酰亚胺氰酸酯树脂固化工艺的研究［J］. 玻璃钢/ 复合材料, 2008, (2):3537.
［6］ YingQiang Zhang, XueNing Shen, FaRong Huang, The preparation and cure reaction kinetics of benzocyclobuteneterminated imide model compounds［J］. J. Appl. Polym. Sci., 2006, 99:17051719.
［7］ Yingqiang Zhang, Xuening Shen, Farong Huang. Thermal stability and degradation products analysis of benzocyclobuteneterminated imide polymers［J］. Thermochimica ACTA, 2005, 430.12, 1522
［8］王靖，沈学宁，黄发荣．苯并环丁烯及其材料(Ⅰ) ［J］. 玻璃钢/ 复合材料, 2002, (2):5053
［9］王靖，沈学宁，黄发荣．苯并环丁烯及其材料(Ⅱ) ［J］. 玻璃钢/ 复合材料,2002, (3):4449.
［10］张英强，郑康生，王霞等，烯丙基化合物对双马来酰亚胺树脂的改性研究［J］.玻璃钢/复合材料，2009，（3）.
［11］张英强,徐耀民，郑康生等.苯并环丁烯封端的聚酰亚胺树脂的流变性能研究［J］.玻璃钢/ 复合材料,2009, (4).
［12］谢倩,包春磊,符新.苯并噁嗪化合物的研究进展［J］.热带农业科学，2004,24(4):5966.
［13］李胜方,付继芳,王洛礼.苯并噁嗪化合物的研究进展［J］.精细石油化工进展,2004,5(8):4752
［14］向海,顾宜.新型酚醛化合物苯并噁嗪化合物的研究进展［J］.高分子材料科学与工程,2004,20(3): 14
［15］王旭，徐日炜，余鼎声等.溶液法合成烯丙基苯并噁嗪化合物与其固化性能的研究［J］. 北京化工大学学报，2003，30（4）：3336.
［16］ Ishida H, Rodrigue Y.Curing Kinetics of a new benzoxazinebased phenolic resin by diferential scanning calorimetry［J］. Appl. Polym. Sci., l995, 58:175l1761
［17］ N.N. Ghosh1, B. Kiskan, Y. Yagci. PolybenzoxazinesNew high performance thermosetting resins: Synthesis and properties［J］. Prog. Polym. Sci., 2007, (32) :13441391

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