THE EFFECTS OF CARBON BLACK ON THE PROPERTY OF PEROXIDECROSSLINKED POLYETHYLENE

Abstract

Abstract: Peroxide-crosslinked polyethylene (XLPE) was obtained with LDPE as base material, carbon black (CB), dicumyl peroxide (DCP) and antioxidant as assistants. The influences of CB content on XLPE′s properties including mechanics, electricity, thermal stability and weather resistance were studied by tension machine, insulating oil dielectric tester, schering bridge, high resistance meter,thermal aging oven,Xenon weatherometer et al. It was found that,with increasing of concentration of carbon black, mechanical property had no obvious change; weather resistance were improved notably; electric strength and volume resistivity gradually decreased;relative permittivity and dielectric dissipation factor increased obviously. When carbon black content was 1.8%, the insulating property and weather resistance approached optimal balance. And, using compounds of carbon black and certain sulfur-containing antioxidants, the thermal aging property of XLPE was significantly improved.

Key words: carbon black, XLPE, peroxide, properties

CLC Number:

TB332

YANG Chang-long, ZHENG Wei, BIAN Jian-jian. THE EFFECTS OF CARBON BLACK ON THE PROPERTY OF PEROXIDECROSSLINKED POLYETHYLENE[J]. Fiber Reinforced Plastics/Composites, 2016, 0(6): 44-47.

References

[1] 罗志强. 10kV交联聚乙烯电缆用绝缘料研制[J]. 邵阳高等专科学校学报, 2000, 13(2): 207-210.
[2] 张建耀. 交联聚乙烯绝缘料用基础树脂的性能研究[J]. 塑料科技, 2005(6): 24-27.
[3] 刘新民, 许春霞, 葛涛, 等. 过氧化物交联聚乙烯的力学性能研究[J]. 现代塑料加工应用, 2003, 15(6): 14-17.
[4] 王亦农. 低密度聚乙烯/炭黑复合材料的制备与性能研究[J]. 江西教育学院学报, 2012, 33(3): 39-41.
[5] 闫志雨, 韩宝忠, 赵洪, 等. 炭黑/交联聚乙烯纳米复合材料的空间电荷和电导特性[J]. 高电压技术, 2014, 40(9): 2661-2667.
[6] Amin AR. Synergistic Effect of TNPP and Carbon Black in Weathered XLPE Materials[J]. J Polym Environ, 2009, 17(4): 267-272.
[7] 刘岩, 鲍文波, 高广刚, 等. 碳黑对紫外光交联聚乙烯材料的屏蔽作用[J]. 塑料工业, 2015, 43(2): 86-88.
[8] 喻金芳, 王玉兴, 陈冰冰, 等. 炭黑对聚乙烯电缆护套料性能影响的探讨[J]. 浙江化工, 1994, 4(25): 28-31.
[9] Mwila J,Miraftab M, Horrocks A.R.Effect of carbon black on the oxidation of polyolefins-An overview[J]. Polymer Degradation and Stability,1994,44(3):351-356.
[10] Goldberg V.M., KolesnikovaN.N., PavermanN.G., et al. Gelbin M.E.Thermo-oxidative degradation of linear low density poly(ethylene) in the presence of carbon black: a kinetic approach[J]. Polymer Degradation and Stability, 2001,74(2):371-385.
[11] Ghaffari M, Ahmadian V. Investigation of antioxidant and electron beam radiation effects on the thermal oxidation stability of low-density polyethylene[J]. Radiation Physics and Chemistry, 2007, 76(11-12):1666-1670.
[12] 刘旭升, 温晓葵, 翁起阳, 等. 抗氧剂736与炭黑复合体系在聚乙烯电缆料中抗热氧效能评价[J]. 合成材料老化与应用, 2015, 44(5): 49-53.
[13] 刘旭升, 温晓葵, 翁起阳, 等. 抗氧剂736与炭黑复合体系在聚乙烯电缆料中抗热氧效能评价[J]. 合成材料老化与应用, 2015, 44(5): 49-53.
[14] 刘春林, 承民联, 宋平生, 等. 过氧化物交联聚乙烯的研究[J]. 现代塑料加工应用, 1997, 10(2): 14-17.
[15] 王斌, 王庆, 钟思智. 硫代受阻酚类抗氧剂[J]. 合成材料老化与应用, 2007, 36(4): 43-46.