COMPOSITES SCIENCE AND ENGINEERING ›› 2024, Vol. 0 ›› Issue (5): 58-65.DOI: 10.19936/j.cnki.2096-8000.20240528.009

• BASIC STUDY • Previous Articles     Next Articles

Effect of SiC fiber preforms structure on densification and mechanical properties of SiCf/BN/SiC composites

WANG Mengqian1, JIA Lintao2, LI Aijun2,3*, PENG Yuqing3   

  1. 1. Eighth Research Institute of Nuclear Industry, Shanghai 201800, China;
    2. Shaoxing Institute of Technology, Shanghai University, Shaoxing 312000, China;
    3. School of Materials Science and Enginnering, Shanghai University, Shanghai 200444, China
  • Received:2023-10-07 Online:2024-05-28 Published:2024-06-17

Abstract: In order to study the effect of silicon carbon (SiC) fiber preform structure on the densification process of SiC matrix by chemical vapor deposition (CVI) process, the pore structure evolution of SiC preform with 2D, 2.5D and 3D structures during the densification process was analyzed using simulation method; and SiCf/BN/SiC composites with three kinds of SiC fiber preform structures were prepared by CVI process using boron trichloride-ammonia-hydrogen-nitrogen (BCl3-NH3-H2-N2) and trichloromethylsilane-hydrogen (MTS-H2) gas mixture as precursor. The results show that the densification efficiency of SiCf/BN/SiC composites varies with SiC fiber preforms structure. The densification rate of 2.5D preform and 3D preform is the fastest and the slowest, respectively. After 120 h, the density of three kinds of structure SiCf/BN/SiC composites was more than 2.3 g/cm3 and the porosity was about 10%. The tensile strength of the three kinds of SiCf/BN/SiC composites was 130~170 MPa. In the process of interlaminar shear, 2D SiCf/BN/SiC composites and 2.5D SiCf/BN/SiC composites showed fiber stripping in XY plane, while 3D SiCf/BN/SiC composites showed the highest interlaminar shear strength and the fracture of orthogonal Z-direction fibers occurred. Therefore, the densification process and mechanical properties of the composite were affected by the SiC fiber preform structure.

Key words: SiC fiber, preform structure, SiC matrix, CVI, densification, composites, mechanical properties

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