Study on properties of domestic high thermal conductivity mesophase asphalt-based carbon fiber composites

doi:10.19936/j.cnki.2096-8000.20250228.006

Abstract

Abstract: In order to consolidate the engineering application foundation of domestic high thermal conductivity mesophase asphalt-based carbon fiber (MPCF) in aerospace field, the properties of domestic MPCF and its composites were studied. The micro-morphology of domestic MPCF was characterized by scanning electron microscopy (SEM) and atomic force microscopy (AFM). The surface chemical elements, wettability and surface energy of domestic MPCF were measured by X-ray photoelectron spectroscopy (XPS), optical microscopy and surface interface testing instrument. The preparation process of domestic MPCF prepreg was investigated. The mechanical properties, physical and chemical properties and thermal vacuum degassing properties of domestic MPCF composites were evaluated. The results show that the roughness of domestic MPCF is higher than that of imported MPCF. The surface chemical activity, wettability and surface energy of domestic MPCF are better than those of imported MPCF. The forming process of domestic MPCF prepreg is subpar, and the interlayer shear strength of domestic MPCF composite (46.69 MPa) is comparable to that of imported MPCF composite, but other properties such as tensile, compression and bending properties are slightly lower than those of imported composite. The thermal vacuum degassing performance of domestic MPCF composite meets the requirements of space environment. The average in-plane thermal conductivity of domestic MPCF isotropic composite material is 152.1 W·m^-1·K^-1, and the thermal conductivity is slightly lower than that of imported materials, but it has more advantages of lightweight and structural-functional integration than the traditional 6063 aluminum alloy heat-expanding structure.

Key words: domestic, MPCF, composite, property

CLC Number:

TB332

XU Xiaokui, PAN Jiang, HAO Shang, ZHANG Juanjuan, WU Chunyan, LIU Qianli. Study on properties of domestic high thermal conductivity mesophase asphalt-based carbon fiber composites[J]. COMPOSITES SCIENCE AND ENGINEERING, 2025, 0(2): 40-45.

References

[1] 高峰阁, 迟卫东, 张鸿翔, 等. 国内外MPCF发展概况与展望[J]. 高科技纤维与应用, 2015, 40(5): 33-37.
[2] 武云, 初人庆. 中间相沥青的应用研究进展[J]. 当代化工, 2020, 49(6): 1189-1192.
[3] 贾真真. 高导热沥青基碳纤维制备过程中的结构演变与性能研究[D]. 北京: 北京化工大学, 2021.
[4] 韩笑, 徐国财, 姚宝慧, 等. 沥青基碳纤维的制备及应用研究进展[J]. 安徽化工, 2011, 37(4): 7-9.
[5] 张建宝, 尚呈元, 周宇, 等. T800/607低温复合材料应用评价研究[J]. 复合材料科学与工程, 2020(2): 97-100.
[6] 王婷婷, 顾轶卓, 王绍凯, 等. 碳纤维轴向导热性能表征及其影响因素[J]. 北京航空航天大学学报, 2017, 43(9): 1931-1938.
[7] 邹豪, 李伟东, 彭公秋, 等. 高模型碳纤维的发展现状及其在航天领域的应用[J]. 合成纤维, 2017, 46(6): 17-22.
[8] 杨燕宁, 张亮儒, 董经经, 等. 高模量碳纤维复合材料在卫星结构上的应用[J]. 高科技纤维与应用, 2022, 47(4): 11-15.
[9] 王忠强. 基于碳纤维复合材料的立方体卫星结构热控一体化设计[D]. 南京: 南京理工大学, 2017.
[10] 陈晓妍, 刘千立, 戴晶滨, 等. 中间相沥青基碳纤维表面特性和界面黏结性能[J]. 上海航天(中英文), 2022, 39(6): 96-101, 124.
[11] 姚远. 中间相沥青基碳纤维及其在飞机上的应用[J]. 纤维复合材料, 2018, 35(3): 73-76.
[12] 李威, 郭权锋. 碳纤维复合材料在航天领域的应用[J]. 中国光学, 2011, 4(3): 201-212.
[13] 李子晗. 中间相沥青基碳纤维复合材料研究进展及发展前景[J]. 新型工业化, 2022, 12(8): 174-177.
[14] 叶崇. 高导热中间相沥青碳纤维的制备及结构调控[D]. 长沙: 湖南大学, 2021.
[15] 吴洋, 杨在峰. 中间相沥青基碳纤维研究进展[J]. 化学工程师, 2023, 37(5): 81-84.
[16] 贺文晋, 张晓欠, 刘丹, 等. 沥青基碳纤维制备研究进展[J]. 煤化工, 2019, 47(4): 72-75, 81.
[17] 曹玉倩, 张建国, 康延涛, 等. 中间相沥青基碳纤维原丝用油剂的研究现状[J]. 化工新型材料, 2023, 51(9): 243-247.
[18] 张媛媛, 初人庆, 郭丹, 等. 高性能沥青基碳纤维发展现状及制备工艺[J]. 当代化工, 2023, 52(2): 457-460.
[19] 史景利, 马昌. 沥青基碳纤维的研发及产业化[J]. 高科技纤维与应用, 2014, 39(3): 7-14.
[20] 刘金港, 翟港港, 田永胜, 等. 各向同性纺丝沥青及其碳纤维的制备与应用研究进展[J]. 化工新型材料, 2023, 51(7): 12-20.
[21] 张亚东, 崔健, 陈旭. 沥青基碳纤维制备及应用研究进展[J].广东化工, 2022, 49(9): 64-65, 77.
[22] 徐保明, 张家晖, 唐强, 等. 沥青基炭纤维制备方法研究进展[J]. 炭素技术, 2017, 36(5): 5-8.
[23] 王一超, 李鹏, 周菊萍. 跨厚比对碳纤维复合材料三点弯曲性能的影响[J]. 复合材料科学与工程, 2023(3): 83-88.