EVALUATION OF A HIGH TEMPERATURE-RESISTANT BISPHENOL A TYPE 2H-CHROMENE RESINS AS THE MATRIX OF COMPOSITES

Abstract

Abstract: Bisphenol A type 2H-bichromene resins (BCA resins) were successfully prepared by heating bipropargyl ether bisphenol A (BPA) in infrared-ray oven at 185℃ for 3h. The curing behaviors of BCA resins were studied by differential scanning calorimetry (DSC). It showed the cured enthalpy was decreased to 620J/g for BCA resin. Thermal stability of the cured BCA resin was also investigated by thermal gravimetric analysis (TGA). The results of TGA revealed that the cured BCA resin possessed excellent thermal stability. Based on the BCA resins, the glass fiber reinforced composites were prepared via press molding process. In comparison of Epoxy matrix composites, the composites of BCA resins presented higher mechanical properties. The flexural strength, flexural modulus and shear strength reached to 580MPa, 24. 7GPa and 40MPa respectively. In additional, the result of dynamic mechanical thermal analysis (DMTA) indicated composite had excellent thermal stability.

Key words: 2H-chromene, propargyl, composites, infrared heating

CLC Number:

CHENG Kai, YANG Guang, GAO Long-fei. EVALUATION OF A HIGH TEMPERATURE-RESISTANT BISPHENOL A TYPE 2H-CHROMENE RESINS AS THE MATRIX OF COMPOSITES[J]. COMPOSITES SCIENCE AND ENGINEERING, 2013, 0(6): 44-47.

References

[1] Zhen Dai,Yanfang Li,Shuguang Yang,Ning Zhao,Xiaoli Zhang,Jian Xu.Kinetics and thermal properties of epoxy resins based on bisphenol fluorene structure[J]. European Polymer Journal,2009,45(7): 1941-1948.
[2] 吕金艳,王雷,柴红梅. 低粘度中温固化环氧树脂体系的基本性能[J]. 玻璃钢/复合材料,2008,(4): 16-18.
[3] 刘俐,王钧,李静,徐任信. 呋喃改性胺固化环氧树脂的耐强碱性研究[J]. 玻璃钢/ 复合材料,2011,(3): 38-41.
[4] 段国红,赵玉英,王二兵. 双酚A 型环氧树脂胶粘剂的合成及配制[J]. 化工时刊,2011,26(12): 12-16.
[5] 钱军民,李旭祥. 环氧树脂改性研究进展[J]. 工程塑料应用,2001,10(29): 50-53.
[6] 洪旭辉,李亚锋. 氰酸酯改性环氧树脂耐热性研究[J]. 热固性树脂,2009,24(5): 14-17.
[7] 陈平,程子霞,朱兴松,雷清泉. 环氧树脂与氰酸酯共固化产物性能的研究[J]. 复合材料学报,2011,18(3): 10-13.
[8] Inbasekaran,M. N.,Dirlikov,S. K.Process for making propargyl ethers of bisphenols[P]. US Patent: 4885403,1989.
[9] Liu F,Li W,Wei L,Zhao T.Bismaleimide modified bis propargyl ether bisphenol A resin: Synthesis,cure,and thermal properties[J]. Journal of Applied Polymer Science, 2006, 102(4):3610-3615.
[10] Kolb G. C.,City,B.,M. Scheck,D. Midland,Stoil Dirlikov,Ypsilanti,Inbasekaran,M.,Godschalx,J. P. Polymer resulting from the cure of a preformed chromene-containing mixture[P]. US Patent No. 5155196,1990.
[11] Pastine S. J.,Youn S. W.,Sames,D.PtIV-catalyzed cyclization of arene-alkyne substrates via intramolecular electrophilic hydroarylation[J].Organic Letters,2003,5(7): 1055-1058.
[12] Pastine S. J.Pt(IV)-catalyzed cyclization of arene-alkyne substrates via C-H bond functionalization[J]. Tetrahedron,2003,59(45): 8859-8868.
[13] Véchot,L.,Bombard,I.,Laurent,P.,Lieto,J.Experimental and modeling study of the radiative curing of a polyester-based coating[J]. International Journal of Thermal Sciences, 2006, 45(1): 86-93.
[14] Bombard,I.,Laurent,P.,Lieto,J.,Jeandel,G.A model of the infrared cure of powder coatings based on surface absorptivities insitu measurements[J]. Journal of Coatings Technology and Research,2008,5(3): 353-363.
[15] Basu S. K.,Shah,B.,Kia H. G.The effect of oven-heat flux on powder-coating issues of sheet molding compound panels[J].Industrial & Engineering Chemistry Research,2009,48(3):1638-1649.
[16] 孟秀青,张静,陈伟明,王锋. RTM 成型用高性能环氧树脂基体的研究[J]. 玻璃钢/复合材料,2011,(1): 33-35.
[17] 艾静,宁荣昌,王青松. 中温固化单组分EP 结构胶的研究[J]. 中国胶黏剂,2011,20(10): 45-48.
[18] 廖子龙,乌云其其格. 环氧树脂/玻璃纤维复合材料性能研究与应用[J]. 工程塑料应用,2008,36(9): 47-9.
[19] 王春齐,江大志,曾竟成,袁志庆,肖加余. 温度和压力对玻璃纤维增强环氧复合材料吸湿特性的影响[J]. 国防科技大学学报,2010,32(2): 40-45.
[20] 李泽文,张凌,杨巍,张贞浴. 动态力学分析法用于评价环氧树脂基体与复合材料耐热性的研究[J]. 纤维复合材料,2009,(2): 13-17.