PREPARATION AND CHARACTERIZATION OF POLYIMIDE/TiO2 COMPOSITE FILM

Abstract

Abstract: Polyimide/TiO₂composite films were prepared via sol-gel reaction using tetrabutyl titanate (TBT) as the inorganic precursor and incorporating it into poly (amic acid) (PAA) derived from 3,3',4,4'-biphenyl tetracarboxylic diandhydride (BPDA)and 4,4'-diaminodiphenyl ether (ODA) in N,N-dimethylacetamide (DMAc). The chemical structure and compatibility of the hybrid film were characterized by FFIR and SEM, respectively. The effect of TiO₂ content on mechanical property and thermal behavior of hybrid film was studied. The results indicated that the nano TiO₂ particles dispersed uniformly in polyimide matrix. And the comprehensive properties were optimal when the content of TiO₂ is about 2wt.%.

Key words: polyimide, TiO₂, composite film

CLC Number:

TB332

YANG Zhi-lan. PREPARATION AND CHARACTERIZATION OF POLYIMIDE/TiO₂ COMPOSITE FILM[J]. COMPOSITES SCIENCE AND ENGINEERING, 2015, 0(10): 10-13.

References

[1] Rabilloud G. High-performance polymers: polyimides in electronics NO. 3: chemistry and applications. Paris: editions Technip,
[2] 2000.
[3] Gosh MK, Mittal KL. Polyimides: fundamentals and application. New York: Marcel Derkker, 1996.
[4] Feger CK, Khojasteh MM, McGrath JE. Polyimides: chemistry and characterization. Amsterdam: Elsevier, 1994.
[5] Mallakpour, S., Dinari, M.. Novel nanocomposites based on reactive organoclay of L-tyrosine and amine end-capped poly(amide-imide):Synthesis and characterization. Appl. Clay. Sci., 2013, 75-76, 67-73.
[6] Mallakpour, S., Dinari, M.. High performance polymers in ionic liquid: a review on prospects for green polymer chemistry. Part II: Polyimides and polyesters. Iran. Polym. J., 2011, 20: 259-279.
[7] Mohammad A. Wahab, Il Kim, Chang-Sik Ha. Microstructure and properties of polyimide/poly(vinylsilses-quioxane)hybrid composite films. Polymer, 2003, 44: 4705-4713.
[8] 李白存. 聚酰亚胺-无机物杂化节能玻璃贴膜的制备及性能研究. 西安: 西北大学, 2010.
[9] 王月. 聚酰亚胺银复合纤维的制备与性能研究. 北京: 北京化工大学, 2011.
[10] 张明玉, 刘立柱, 翁凌, 等. 离子交换法制备聚酰亚胺/氧化铝复合薄膜及性能研究. 功能材料, 2013, (5):740-743.
[11] 牟书香. 聚酰亚胺表面功能化复合材料的制备及结构与性能研究. 北京: 北京化工大学,2010.
[12] 范勇, 李彦如, 陈昊. 纳米杂化聚酰亚胺薄膜耐电晕和击穿场强研究进展. 哈尔滨理工大学学报, 2012, 17 (1): 1-5.
[13] Peng Zhang, Li Chen, Gaoqiang LI, et al. Enhangcement of properties of polyimide/silica hybrid nanocomposites by benzimidazole formed hydrogen bond. Polymers for Advanced Technologies, 2012, 23 (10):1362-1368.
[14] Xiaoxu Liu, Jinghua Yin, Yunan Kong, et al. The property and microstructure study of polyimide/nano-TiO₂ hybrid films with sandwich structures. Thin Solid Films, 2013, 544: 54-58.
[15] Yuejin Tong, Yuesheng Li, Fengchao Xie, et a1. Preparation and characteristics of polyimide TiO₂nanocomposite film. Polym Int, 2000, 49(11): 1543-1547.
[16] LIU Li,LU Qing-hua,YIN Jie,et al.Preparation and properties of photosensitive polyimide/titania-silica hybrid materials. Material Science and Engineering: C, 2002, (22): 61-65.

PREPARATION AND CHARACTERIZATION OF POLYIMIDE/TiO₂ COMPOSITE FILM

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	YAN Jiqiang, XIE Zongyou, LI Jun, ZOU Qi, LEI Shuai, CAO Tienan, ZHANG Daijun. Effect of ply angle on anti-high speed impact properties of polyimide fiber reinforced composites [J]. COMPOSITES SCIENCE AND ENGINEERING, 2024, 0(9): 12-18.
[2]	LI Chunman, LI Shuangwen. Preparation and performance research of anisotropic fluorinated polyimide/carbon nanotubes composite films [J]. COMPOSITES SCIENCE AND ENGINEERING, 2023, 0(8): 51-56.
[3]	NI Hong-jiang, LI Jun, XING Yu, DAI Xiao-xiang, ZHANG Dai-jun, CHEN Xiang-bao. Preparation and properties of T800-class carbon fiber reinforced polyimide composite for aero engine [J]. COMPOSITES SCIENCE AND ENGINEERING, 2022, 0(5): 46-51.
[4]	LIANG Heng-liang, CHEN Jing, LIU Yu, ZHANG Shou-chun. Study on fabrication technique of new thermal protection structure based on resin matrix composite [J]. COMPOSITES SCIENCE AND ENGINEERING, 2022, 0(3): 96-103.
[5]	WANG Ke-jie, LU Cheng, SHAO Hui-qi, JIANG Jin-hua, CHEN Nan-liang. Effect of carbon nanotubes on the thermal expansion coefficient ofpolyimide homogeneous composite membrane [J]. COMPOSITES SCIENCE AND ENGINEERING, 2022, 0(2): 62-67.
[6]	LONG Xin-xi-ming, PAN Lei, ZHANG Hao-ran, GAO Li-xin, WANG Ruo-fan. Preparation and properties study of B₄C/PI composite for neutron radiation protection [J]. COMPOSITES SCIENCE AND ENGINEERING, 2022, 0(10): 50-55.
[7]	LIANG Heng-liang, ZHOU Hong-fei, CHEN Jing. Research on the curing packaging technology of high temperature polyimide composites [J]. COMPOSITES SCIENCE AND ENGINEERING, 2022, 0(1): 112-116.
[8]	LIN Ting-ting, SHAO Hui-qi, JIANG Jin-hua, CHEN Nan-liang, LIU Shi-hai. The effect of high temperature on the tensile properties and structure of several organic high-performance fibers [J]. COMPOSITES SCIENCE AND ENGINEERING, 2021, 0(8): 44-49.
[9]	LIANG Heng-liang, ZHOU Hong-fei, SUN Ke-han. Research on process of T300 carbon fiber/BMP370 polyimide composites and its properties [J]. COMPOSITES SCIENCE AND ENGINEERING, 2021, 0(12): 95-98.
[10]	XING Yi-long, ZHAO Xin, LI Meng. ELECTROMAGNETIC SHIELDING EFFECTIVENESS OF GNP/CNT/EP COMPOSITE FILMS [J]. COMPOSITES SCIENCE AND ENGINEERING, 2021, 0(1): 52-57.
[11]	ZHANG Chen-qian, LI Shao-liang, ZHAI Quan-sheng, YE Hong-jun. EFFECT OF METAL MESH COMPOSITE FILM ON CURING DEFORMATION OF ZT7H/5429 COMPOSITE PLATE [J]. Composites Science and Engineering, 2020, 0(7): 103-109.
[12]	XIA Yu, WANG Dong, XU Kong-li, WU Xiao. STUDY ON PREPARATION AND PROPERTIES OF NOVEL RESIN-BASED THERMAL PROTECTION STRUCTURES [J]. Composites Science and Engineering, 2020, 0(10): 96-100.
[13]	ZHANG Rong, PEI Xue-liang, XI Xian-feng, OUYANG-Qin. STUDY ON THE PREPARATION AND INTERFACE PERFORMANCE OF O₃-OXIZED CARBON FIBER/POLYIMIDE COMPOSITES [J]. Fiber Reinforced Plastics/Composites, 2019, 0(3): 21-25.
[14]	GAO Long-fei, LI Song, XIAO Yuan-yu, ZHANG Xue-mei. RESEARCH OVERVIEW OF FIBER REINFORCED PMR POLYIMIDE MATRIX COMPOSITES [J]. Fiber Reinforced Plastics/Composites, 2018, 0(9): 106-110.
[15]	HU Ai-Jun , LI Ke-di, LI Shu-shu , YANG Shi-yong. INFLUENCE OF MOLECULAR STRUCTURE ON MELT VISCOSITY AND FEATURES OF POLYIMIDE FOAM [J]. Fiber Reinforced Plastics/Composites, 2017, 0(1): 36-43.