THE INFLUENCE OF NANO-SiO2 AND PP-g-MAH ON THE PROPERTIES OF GLASS FIBER REINFORCED PP COMPOSITES

Abstract

Abstract: The interfacial bonding strength between fiber and resin is the key factor that determines the performance of composite materials. In this paper, we will study the influence of glass fiber surface coated with nano-SiO₂ that was treated by silane coupling agent KH550 and PP-g-MAH addition in PP on the interfacial bonding strength and mechanical properties of glass fiber reinforced polypropylene composites. The results show that KH550 surface treatment can reduce the surface energy of nano-SiO₂, which makes the nano-SiO₂ be advantageous to disperse on fiber surface. Fiber surface coated with nano-SiO₂ and addition of PP-g-MAH in PP is helpful to enhance the interfacial bonding strength between the fiber and resin. Meanwhile, shear strength of composite increased by 116.06%, tensile strength increased by 109.14%, and bending strength increased by 99.85%.

Key words: interfacial bonding strength, nano-SiO₂, PP-g-MAH, glass fiber reinforced composites

CLC Number:

TB332

YANG Jian-jun, HE Ya-dong, ZHANG Zhi-cheng, XIN Chun-ling. THE INFLUENCE OF NANO-SiO₂ AND PP-g-MAH ON THE PROPERTIES OF GLASS FIBER REINFORCED PP COMPOSITES[J]. Fiber Reinforced Plastics/Composites, 2016, 0(9): 49-54.

References

[1] 田永,韦俊. 车用聚丙烯及其复合材料的性能与应用[J]. 汽车零部件, 2012(6): 66-70.
[2] 杜善义. 先进复合材料与航空航天[J]. 复合材料学报, 2007, 24(1): 1-12.
[3] 方鲲, 张国荣, 吴丝竹, 等. 长纤维增强热塑性复合材料在汽车零配件上的应用进展[J]. 中国塑料, 2009, 23(3): 13-18.
[4] 王秋峰, 周晓东, 侯静强. 长纤维增强热塑性复合材料的浸渍技术与成型工艺[J]. 纤维复合材料, 2006, 23(2): 43-46.
[5] 周效谅, 钱春香, 王继刚, 等. 连续纤维增强热塑性树脂基复合材料拉挤工艺研究与应用现状[J]. 高科技纤维与应用, 2004, 29(1): 41-45.
[6] 吴靖. 国外热塑性树脂基复合材料现状及发展趋势[J]. 材料导报, 1995, 18(1): 77-80.
[7] 中国玻璃纤维工业协会, 中国复合材料工业协会. 纤维复合材料行业“十三五”发展规划[J]. 玻璃钢, 2015(3): 22-34.
[8] Beyerlein I J, Demkowicz M J, Misra A, et al. Defect-interface interactions[J]. Progress in Materials Science, 2015, 74: 125-210.
[9] Thomason J L, Schoolenberg G E. An investigation of glass fibre/polypropylene interface strength and its effect on composite properties[J]. Composites, 1994, 25(3): 197-203.
[10] 周祝林, 姚辉, 孙佩琼, 等. 树脂基纤维复合材料界面理论评述[J]. 玻璃钢, 2006(1): 29-33.
[11] 黄玉东, 魏月贞. 复合材料界面研究现状(上)[J]. 纤维复合材料, 1993(3): 5-13.
[12] 伍章健. 复合材料界面和界面力学[J]. 应用基础与工程科学学报, 1995(3): 85-97.
[13] Etcheverry M, Barbosa S E. Glass fiber reinforced polypropylene mechanical properties enhancement by adhesion improvement[J]. Materials, 2012, 5(6): 1084-1113.
[14] Karger-Kocsis J, Mahmood H, Pegoretti A. Recent advances in fiber/matrix interphase engineering for polymer composites[J]. Progress in Materials Science, 2015, 73: 1-43.
[15] 严志云, 石虹桥, 梁世强, 等. 聚合物复合材料界面粘合理论研究进展[J]. 仲恺农业技术学院学报, 2007, 20(2): 66-69.
[16] 余剑英, 周祖福, 赵青南, 等. 氨基硅烷/马来酸酐接枝聚丙烯界面化学反应的研究[J]. Chinese Journal of Chemical Physics, 2000, 13(1): 109-112.
[17] 张志谦, 龙军, 刘立洵, 等. 玻璃纤维增强聚丙烯复合材料界面改性研究[J]. 宇航材料工艺, 2002, 32(4): 28-31.
[18] Shen Chou, Lingshiou Lin. Effect of colloidal silica on adhesion of glass fibers to polypropylene[J]. Polymers & Polymer Composites, 2001, 9(3): 175-183.
[19] Romanov V, Lomov S V, Verpoest I, et al. Inter-fiber stresses in composites with carbon nanotube grafted and coated fibers[J]. Composites Science and Technology, 2015, 114: 79-86.
[20] 张玲, 杨建民, 冯超伟, 等. 表面复合纳米SiO₂和碳纳米管玻璃纤维增强尼龙6的结构与性能[J]. 高分子学报, 2010(11): 1333-1339.
[21] 高正楠, 江小波, 郭锴. KH550的水解工艺及其对SiO₂表面改性的研究[J]. 北京化工大学学报(自然科学版), 2012, 39(2): 7-12.

THE INFLUENCE OF NANO-SiO₂ AND PP-g-MAH ON THE PROPERTIES OF GLASS FIBER REINFORCED PP COMPOSITES

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 2

Recommended Articles

Metrics

Comments

[1]	LIU Shuaiwen, SHEN Jinrong, JI Xinzhu, ZHANG Qiangxian, FANG Yuan. Tension-tension fatigue properties of surface-functionalized multi-walled carbon nanotubes modified glass fiber reinforced resin matrix composites [J]. COMPOSITES SCIENCE AND ENGINEERING, 2023, 0(8): 92-100.
[2]	ZHAO Peng-fei, FANG Yuan, LIU Wei-qing, XU Dan-yang. EXPERIMENTAL STUDY ON BONDING PROPERTY OF GFRP-PAULOWNIA IN THE HYGROTHERMAL ENVIRONMENT [J]. Fiber Reinforced Plastics/Composites, 2017, 0(4): 49-53.