RESEARCH DEVELOPMENT OF GLASS FIBRE REINFORCED NYLON 6 COMPOSITES

Abstract

Abstract: Research development about factors influencing property of nylon 6(PA6)/ glass fibre (GF) composites, compounding process of the composites, interphase treatment, and synergism modification of GF and third component on PA6 were reviewed in this study. The increase of GF content is propitious to improve mechanics and tribology property of PA6/GF composites. The improvement effect of long GF on the composites is better than that of short GF. Surface treatment of silane coupling agent, rare earths and compatibilizer on GF is conducive to improve interface combine strength, and increase integration property of the composites. Addition of nanometer SiO₂ and Si₃N₄ into PA6/GF composites is propitious to improve mechanics and tribology property of the composites, and addition of nanometer clay is able to improve its mechanics and flame retardant property. Addition of carbon nanotubes into the composites is not only able to improve its mechanics property, but also able to improve its antistatic and flame retardant property. Addition of styrene/acrylonitrile/maleic anhydride copolymer and polythene into the composites is conducive to depress its hygroscopicity, and addition of UHMWPE is able to improve its tribology property. Flame retardant containing phosphorus and GF have synergism effect on improvement of flame retardant property of the composites.

Key words: nylon 6, glass fibre, compounding process, interphase modification, synergism modification

CLC Number:

LI Yue-wen. RESEARCH DEVELOPMENT OF GLASS FIBRE REINFORCED NYLON 6 COMPOSITES[J]. COMPOSITES SCIENCE AND ENGINEERING, 2015, 0(11): 85-89.

References

[1] 张士华, 陈光, 崔崇, 等. 玻璃纤维增强MC尼龙复合材料的摩擦磨损性能研究. 摩擦学学报,2006,26(5):452-455.
[2] 杨小燕, 周云港, 叶红梅, 等. 反应挤出玻璃纤维增强PA6工艺初探. 现代塑料加工应用,2008,20(6):36-39.
[3] 谢莹, 李笃信, 赵丽, 等. GF增强PA6复合材料的力学与摩擦性能研究. 工程塑料应用,2010,38(11):12-15.
[4] 崔峰波. 长玻璃纤维增强尼龙复合材料的制备及性能研究. 杭州:浙江大学硕士毕业论文,2011.1-49.
[5] 刘庆辉. 玻璃纤维增强PA6复合材料性能研究. 长春:长春工业大学硕士毕业论文,2012. 1-44.
[6] Kuram E, Tasci E, Altan A I, et al. Investigating the effects of recycling number and injection parameters on the mechanical properties of glass-fibre reinforced nylon 6 using Taguchi method. Materials & Design, 2013, 49: 139-150.
[7] 张士华, 陈光, 崔崇, 等. 偶联剂处理对玻璃纤维/尼龙复合材料力学性能的影响. 复合材料学报,2006,23(3):31-36.
[8] 杨旭宇. 玻璃纤维改性PA6性能的研究. 塑料科技,2012,40(12): 55-58.
[9] 杨中文, 刘西文, 皮杰, 等. 马来酸单酯稀土包覆硅灰石改性PA6的研究. 工程塑料应用,2008,36(6):9-12.
[10] 李跃文, 欧阳育良. 硅灰石对塑料的改性研究进展. 玻璃钢/复合材料,2008,(4):45-48.
[11] 尹璞. 稀土处理玻璃微珠和短玻纤增强PA6/UHMWPE复合材料的性能. 南京:南京航空航天大学硕士毕业论文,2009. 1-64.
[12] 邹志明, 邵鹏, 蒋智杰, 等. 相容剂对玻纤增强PA6流变行为的影响. 现代塑料加工应用,2005,17(5):28-31.
[13] 金杰, 陈卫, 张玲, 等. 静电吸附制备玻璃纤维/乙烯-马来酸酐共聚物/碳纳米管混杂结构增强PA6复合材料. 高分子学报,2013,(10):1262-1269.
[14] 郑云龙. PA6/玻璃纤维复合材料中界面粘接与分散作用的研究. 湘潭:湘潭大学硕士毕业论文,2006. 1-46.
[15] 张静,何春霞. 纳米SiC和SiO₂与玻璃纤维混杂填充PA6的力学性能及摩擦磨损性能. 材料科学与工程学报,2008,26(6):937-939.
[16] 姜勇, 张平, 尹久仁, 等. 纳米SiO₂与玻璃纤维含量对PA6显微硬度的影响. 高分子材料科学与工程,2009,25(9):54-56.
[17] 张玲, 杨建民, 冯超伟, 等. 表面复合纳米SiO₂和碳纳米管玻璃纤维增强PA6的结构与性能. 高分子学报,2010,(11):1333-1339.
[18] 张静, 何春霞, 路琴. 纳米Si₃N₄与玻璃纤维混杂增强PA6复合材料的摩擦学性能研究. 工程塑料应用,2008,36(6):57-60.
[19] 张士华, 陈光, 崔崇. 玻璃纤维粉煤灰增强尼龙复合材料的制备与性能研究. 塑料工业,2009,37(11):21-24.
[20] Shen Z Q, Bateman S, Wu D Y, et al. The effects of carbon nanotubes on mechanical and thermal properties of woven glass fibre reinforced polyamide-6 nanocomposites. Composites Science and Technology, 2009, 69(2): 239-244.
[21] Isitman N L, Gunduz H O, Kaynak C. Nanoclay synergy in flame retarded/glass fibre reinforced polyamide 6. Polymer Degradation and Stability, 2009, 94(12): 2241-2250.
[22] Shen S Z, Bateman S, Mcmahon P. The effects of clay on fire performance and thermal mechanical properties of woven glass fibre reinforced polyamide 6 nanocomposites. Composites Science and Technology, 2010, 70(14): 2063-2067.
[23] 蔡梓林, 黄汉雄. PA6/MMT/SGF复合材料的流变性能. 工程塑料应用,2010,38(8):39-41.
[24] Yilmaz S, Yilmaz T. Effect of POSS and chain extender on tensile and fracture properties of neat and short glass fiber reinforced polyamide 6 composites. Composites Part A: Applied Science and Manufacturing, 2014, 67: 274-281.
[25] 傅荣政. PA6/ SANMAH/GF复合材料的制备及其性能研究. 工程塑料应用,2005,33(11):10-13.
[26] Malchev P G, Vos G, Norder B, et al. Evolution of the morphology and the mechanical properties of ternary PE/PA6/GF composites during annealing. Polywer, 2007, 48(21): 6294-6303.
[27] Malchev P G, Vos G, Picken S J, et al. Mechanical and fracture properties of ternary PE/PA6/GF composites. Composites Science and Technology, 2010, 70(5): 734-742.
[28] 蔡力锋,王缸荣,林志勇. PA6/ PUR-T/GF复合材料的力学性能研究. 工程塑料应用,2010,38(3):5-7.
[29] Li D X, You Y L, Deng X, et al. Tribological properties of solid lubricants filled glass fiber reinforced polyamide 6 composites. Materials & Design, 2013, 46: 809-815.
[30] Chen Y H, Wang Q. Preparation, properties and characterizations of halogen-free nitrogen-phosphorous flame-retarded glass fiber reinforced polyamide 6 composite. Polymer Degradation and Stability, 2006, 91(9): 2003-2013.
[31] Hu Z, Chen L, Lin G P, et al. Flame retardation of glass-fibre-reinforced polyamide 6 by a novel metal salt of alkylphosphinic acid. Polymer Degradation and Stability, 2011, 96(9): 1538-1545.
[32] 孙向东, 孙旭东, 张慧波, 等. 磨碎玻璃纤维在MC尼龙中的应用研究. 工程塑料应用,2004,32(7):4-7.
[33] 李杨, 罗筑, 鲁圣军, 等. PA6/长玻纤/氯化钙复合材料结构与性能研究. 工程塑料应用,2011,39(12):17-21.