Properties of color carbon fiber prepared by self-assembly deposition of chemically modified graphene oxide

doi:10.19936/j.cnki.2096-8000.20220328.006

Abstract

Abstract: Carbon fiber has been widely used in aviation, aerospace, automotive, energy and other fields due to its high specific strength, high specific modulus and other excellent properties. How to maintain the excellent mechanical properties of carbon fiber composites while taking into consideration its functionality and intelligence has gradually become the future development direction of composites. Graphene oxide (GO) aqueous solution can form a structural color coating similar to one-dimensional photonic crystal through deposition and self-assembly on carbon fiber. However, there is only physical absorbing force between GO coating and carbon fiber, and the interface performance is insufficient. In this paper, GO is chemically modified with silane coupling agent (APTES). The modified GO (mGO) is also deposited on the surface of carbon fibers by self-assembly method to prepare color carbon fibers. The influence of APTES content on interfacial shear strength, tensile mechanical properties and coloring mechanism are investigated. The results show that the introduction of amino functional group in APTES can significantly improve the interfacial bonding property between carbon fiber and GO. mGO with multilayer structure can remedy the surface defects of carbon fiber and improve the strength of monofilament fiber. Compared with GO-CF, the monofilament tensile strength and interfacial shear strength of mGO-CF-15 are increased by 12.4% and 13.5% respectively.

Key words: carbon fiber, graphene oxide, interfacial shear strength, monofilament tensile strength, composites

CLC Number:

TB332

HOU Jing, YANG Chen, LIU Qin-qin, LEI Yan-ni, XU Pei-jun. Properties of color carbon fiber prepared by self-assembly deposition of chemically modified graphene oxide[J]. COMPOSITES SCIENCE AND ENGINEERING, 2022, 0(3): 45-50.

References

[1] GIEBEL E, HERRMANN T, SIMON F, et al. Surface modification of carbon fibers by free radical graft-polymerization of 2-hydroxyethyl methacrylate for high mechanical strength fiber-matrix composites[J]. Macromolecular Materials & Engineering, 2017, 302(12): 1-5.
[2] FRANK E, HERMANUTZ F, BUCHMEISER M R. Carbon fibers: Precursors, manufacturing, and properties[J]. Macromolecular Materials and Engineering, 2012, 297(6): 493-501.
[3] LIU Y, KUMAR S. Recent progress in fabrication, structure, and properties of carbon fibers[J]. Polymer Reviews, 2012, 52(3): 234-258.
[4] CHEN X, WANG X, LI L, et al. Preparation and microwave absorbing properties of nickel-coated carbon fiber with polyaniline via in situ polymerization[J]. Journal of Materials Science Materials in Electronics, 2016, 27(6): 5607-5612.
[5] ABDELAL N. Electromagnetic interference shielding of stitched carbon fiber composites[J]. Journal of Industrial Textiles, 2020, 49(6): 773-790.
[6] DENG C, JIANG J, LIU F, et al. Influence of graphene oxide coatings on carbon fiber by ultrasonically assisted electrophoretic deposition on its composite interfacial property[J]. Surface and Coatings Technology, 2015, 272(4): 176-181.
[7] LIN S, FLEMING J, HETHRINGTON D, et al. A three-dimensional photonic crystal operating at infrared wavelengths[J]. Nature, 1998, 394(6690): 251-253.
[8] 史文静, 张佩华. 热转移压印纳米结构在化学纤维结构显色上的应用和研究[J]. 国际纺织导报, 2008, 36(3): 28-33, 40.
[9] KOLLE M, LETHBRIDGE A, KREYSING M, et al. Bio-inspired band-gap tunable elastic optical multilayer fibers[J]. Advanced Materials, 2013, 25(15): 2239-2245.
[10] LI P, WONG M, ZHANG X, et al. Tunable lyotropic photonic liquid crystal based on graphene oxide[J]. ACS Photonics, 2014, 1(1): 79-86.
[11] PARKER A R, MARTINI N. Structural colour in animals: Simple to complex optics[J]. Optics & Laser Technology, 2006, 38(4-6): 315-322.
[12] TONG L, QI W, WANG M, et al. Tunable design of structural colors produced by pseudo-1D photonic crystals of graphene oxide[J]. Small, 2016, 12(25): 3433-3443.
[13] JALILI R, ABOUTALEBI S H, ESRAFILZADEH D, et al. Organic solvent-based graphene oxide liquid crystals: A facile route toward the next generation of self-assembled layer-by-layer multifunctional 3D architectures[J]. ACS Nano, 2013, 7(5): 3981-3990.
[14] HE L, YE J, SHUAI M, et al. Graphene oxide liquid crystals for reflective displays without polarizing optics[J]. Nanoscale, 2015, 7(5): 1616-1622.
[15] LUO Z, VORA P M, MELE E J, et al. Photoluminescence and band gap modulation in graphene oxide[J]. Applied Physics Letters, 2009, 94(11): 1-3.
[16] SHANG J, LIN M, LI J, et al. The origin of fluorescence from graphene oxide[J]. Scientific Reports, 2012, 2(1): 1-8.
[17] HUANG S Y, WU G P, CHEN C M, et al. Electrophoretic deposition and thermal annealing of a graphene oxide thin film on carbon fiber surfaces[J]. Carbon, 2013, 52(2): 613-616.
[18] ZHANG X, FAN X, YAN C, et al. Interfacial microstructure and properties of carbon fiber composites modified with graphene oxide[J]. ACS Applied Materials & Interfaces, 2012, 4(3): 1543-1552.
[19] WANG C, LI J, YU J, et al. Grafting of size-controlled graphene oxide sheets onto carbon fiber for reinforcement of carbon fiber/epoxy composite interfacial strength[J]. Composites Part A: Applied Science and Manufacturing, 2017, 101(5): 511-520.
[20] 刘秀影, 宋英, 李存梅, 等. 氧化石墨烯接枝碳纤维新型增强体的制备与表征[J]. 无机化学学报, 2011, 27(11): 2128-2132.
[21] 廖俊, 陈圣云, 康宇峰, 等. 硅烷偶联剂及其在复合材料中的应用[J]. 化工新型材料, 2001, 29(9): 26-28.
[22] 王慧茹, 王鑫, 赵雄燕. 硅烷偶联剂改性氧化石墨烯的制备及表征[J]. 应用化工, 2019, 48(1): 105-107.
[23] WU Q, YANG X, WAN Q, et al. Layer-by-layer assembled nacre-like polyether amine/GO hierarchical structure on carbon fiber surface toward composites with excellent interfacial strength and toughness[J]. Composites Science and Technology, 2020, 198(5): 1-24.
[24] 雷振坤, 亢一澜, 王怀文, 等. 单纤维细丝微力学性能实验研究[J]. 实验力学, 2005, 20(1): 72-76.
[25] MRAD M, MONTRMOR M F, DHOUIBI L, et al. Deposition of hybrid 3-GPTMS's film on AA2024-T3: Dependence of film morphology and protectiveness performance on coating conditions[J]. Progress in Organic Coatings, 2012, 73(2-3): 264-271.
[26] PARHIZKER N, SHAHRABI T, RAMEZANZADEH B. A new approach for enhancement of the corrosion protection properties and interfacial adhesion bonds between the epoxy coating and steel substrate through surface treatment by covalently modified amino functionalized graphene oxide film[J]. Corrosion Science, 2017, 123(7): 55-75.
[27] 张双红, 杨波, 孔纲, 等. 氧化石墨烯/硅烷转化膜层的研究进展[J]. 电镀与涂饰, 2020, 39 (11): 733-739.
[28] 南京玻璃纤维研究设计院有限公司. 碳纤维单丝拉伸性能的测定: GB/T 31290—2014[S]. 北京: 中国国家标准化管理委员会, 2014.
[29] WANG C, LI J, SUN S, et al. Electrophoretic deposition of graphene oxide on continuous carbon fibers for reinforcement of both tensile and interfacial strength[J]. Composites Science and Technology, 2016, 135(5): 46-53.
[30] 杜善义, 王晓宏, 张博明, 等. 单丝复合体系界面力学行为的表征[J]. 哈尔滨工业大学学报, 2010, 42(7): 1095-1099.