RESEARCH PROGRESS ON THERMOPLASTIC SIZING AGENT FOR CARBON FIBERS

Abstract

Abstract: Carbon fiber reinforced thermoplastics have been widely used in military and civilian industries, due to their excellent advantages such as toughness and impact resistance, long-term storage of prepregs, short molding cycle and easy recycling. Interface between resin and carbon fiber is one of the key factors to determine the properties of composites, and thermoplastic sizing agent is a critical obstacle that restricts the processing and performance of carbon fiber reinforced thermoplastics. This paper reviews the functions, types and preparation methods of thermoplastic sizing agents, including the interfacial interaction mechanisms between carbon fiber and thermoplastic matrix.

Key words: thermoplastic sizing agent, carbon fiber, composite interface, interface interaction mechanism

CLC Number:

TB332

LU Jia-teng, YAN Chun, XU Hai-bing, CHEN Gang. RESEARCH PROGRESS ON THERMOPLASTIC SIZING AGENT FOR CARBON FIBERS[J]. Fiber Reinforced Plastics/Composites, 2017, 0(6): 94-99.

References

[1] Thomason J L, Adzima L J. Sizing up the interphase: an insider′s guide to the science of sizing[J]. Composites Part A: Applied Science and Manufacturing, 2001, 32(3): 313-321.
[2] Weitzsacker C L, Bellamy M, Sherwood P M A. Studies of the effect of size on carbon fiber surfaces[J]. Journal of Vacuum Science & Technology A, 1994, 12(4): 2392-2397.
[3] 张艳霞. 碳纤维增强尼龙复合材料的研究[D]. 上海: 东华大学学报, 2010(8): 41-44.
[4] 杨序纲. 复合材料界面[M]. 北京: 化学工业出版社, 2010.
[5] Liu W B, Zhang S, Hao L F. Properties of carbon fiber sized with poly (phthalazinone ether ketone) resin[J]. Journal of Applied Polymer Science, 2013, 128(6): 3702-3709.
[6] Yuan H, Zhang S, Lu C. Improved interfacial adhesion in carbon fiber/polyether sulfone composites through an organic solvent-free polyamic acid sizing[J]. Applied Surface Science, 2013, 279: 279-284.
[7] Yuan H, Zhang S, Lu C. Surface modification of carbon fibers by a polyether sulfone emulsion sizing for increased interfacial adhesion with polyether sulfone[J]. Applied Surface Science, 2014, 317: 737-744.
[8] 王成杨. 双马来酰亚胺耐高温碳纤维乳液上浆剂的研制及性能研究[D]. 长春: 吉林大学, 2011.
[9] Saz-Orozco B D, Ray D, Kervennic A, et al. Toughening of Carbon Fibre/Polybenzoxazine Composites by Incorporating Polyethersulfone into the Interlaminar Region[J]. Materials & Design, 2015, 93:297-303.
[10] 吴玉霞, 朱姝, 徐英凯, 等. 纺织结构碳纤维增强尼龙基复合材料的成型加工及力学性能[J]. 高分子材料科学与工程, 2015(10): 92-98.
[11] 潘任行, 王彪, 施云舟. 上浆剂对碳纤维增强尼龙66复合材料结构性能的影响[J]. 东华大学学报: 自然科学版, 2015, 41(1): 6-9.
[12] 裴冠中. 碳纤维表面耐高温上浆剂的工艺研究及其效果评价[D]. 哈尔滨: 哈尔滨工业大学, 2011.
[13] 刘杰, 周秀燕, 梁节英. 磺化聚醚砜上浆剂对碳纤维/聚醚砜复合材料界面性能的影响[J]. 复合材料学报, 2015, 32(2): 420-426.
[14] 刘民英, 赵清香. 碳纤维/PF尼龙复合材料性能及界面研究[J]. 高分子材料科学与工程, 1994, 10(2): 42-47.
[15] Karsli N G, Ozkan C, Aytac A, et al. Characterization of poly (butylene terephthalate) composites prepared by using various types of sized carbon fibers[J]. Materials & Design, 2015, 87: 318-323.
[16] Ozkan C, Karsli N G, Aytac A, et al. Short carbon fiber reinforced polycarbonate composites: Effects of different sizing materials[J]. Composites Part B: Engineering, 2014, 62: 230-235.
[17] Liu Y, Fang Y, Qian J, et al. Bio-inspired polydopamine functionalization of carbon fiber for improving the interfacial adhesion of polypropylene composites[J]. RSC Advances, 2015, 5(130): 128-132.
[18] Liu Y, Zhang X, Song C, et al. An effective surface modification of carbon fiber for improving the interfacial adhesion of polypropylene composites[J]. Materials & Design, 2015, 88: 810-819.
[19] Daigo Kobayashi, Ya-Ting Hsieh, Atsushi Takahara. Interphase structure of carbon fiber reinforced polyamide 6 revealed by microbeam X-ray diffraction with synchrotron radiation[J]. Polymer, 2016, 89: 154-158.
[20] 曾汉民, 孔柏岭. 碳纤维-尼龙1010界面形态的研究[J]. 高分子学报, 1989, 1(1): 75-80.
[21] Han S H, Oh H J, Kim S S. Evaluation of the impregnation characteristics of carbon fiber-reinforced composites using dissolved polypropylene[J]. Composites Science and Technology, 2014, 91: 55-62.
[22] 黄海. 碳纤维/MC尼龙6原位复合材料的制备及结构与性能研究[D]. 华侨大学, 2006.
[23] 杨洪祥, 周存, 徐进云. SiO₂/TiO₂/聚酰亚胺复合杂化环氧树脂基碳纤维浆料的制备与表征[J]. 纺织学报, 2010, 31(5): 63-68.
[24] 吴庆, 陈惠芳. 碳纤维表面处理与上浆综述[J]. 材料导报, 2000, 14(6): 41-42.
[25] 李晓非. PPEK 乳液上浆剂的制备与性能表征[D]. 哈尔滨: 哈尔滨工业大学, 2012.
[26] Park J M, Lee J O, Park T W. Improved interfacial shear strength and durability of single carbon fiber reinforced isotactic polypropylene composites using water-dispersible graft copolymer as a coupling agent[J]. Polymer composites, 1996, 17(3): 375-383.
[27] 曹霞, 温月芳, 张寿春, 等. 耐温型炭纤维乳液上浆剂[J]. 新型碳材料, 2006, 21(04): 337-342.
[28] Tice T R, Gilley R M. Preparation of injectable controlled-release microcapsules by a solvent-evaporation process[J]. Journal of Controlled Release, 1985, 2: 343-352.
[29] Freiberg S, Zhu X X. Polymer microspheres for controlled drug release[J]. International journal of pharmaceutics, 2004, 282(1): 1-18.
[30] Bahri Z E, Taverdet J L. Preparation and optimization of 2, 4-D loaded cellulose derivatives microspheres by solvent evaporation technique[J]. Journal of applied polymer science, 2007, 103(4): 2742-2751.
[31] Giraud I, Franceschi-Messant S, Perez E. Preparation of aqueous dispersion of thermoplastic sizing agent for carbon fiber by emulsion/solvent evaporation[J]. Applied Surface Science, 2013, 266: 94-99.
[32] Liu Z, Tian Y, Kang S. Synthesis and characterization of novel epoxy-modified waterborne polyurethanes and their use in carbon fiber sizing[J]. Journal of Applied Polymer Science, 2012, 125(5): 3490-3499.
[33] Sugiura N, Maki N. water-soluble thermoplastic resin such as a nylon and an amphoteric surfactant, particularly an alkylimidazoline-based betaine type: U.S. Patent 7,135, 516[P]. 2006-11-14.
[34] 周存. 碳纤维水基复合浆料的制备与性能研究[D]. 天津: 天津工业大学, 2011.