COMPOSITES SCIENCE AND ENGINEERING ›› 2023, Vol. 0 ›› Issue (6): 17-22.DOI: 10.19936/j.cnki.2096-8000.20230628.003

• BASIC STUDY • Previous Articles     Next Articles

Preparation of copolyamide water-based sizing agent for carbon fiber and interfacial modification of CF/PA6 composites

WANG Shaofei1, XUE Kanghao1, FAN Lin2, YANG Qing3, LÜ Yueen3, DING Xiaoma3, ZHAO Le1, ZHANG Hui1,4, LIU Yong1,4*   

  1. 1. State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China;
    2. Shanghai Institute of Spacecraft Equipment, Shanghai 201620, China;
    3. Shanghai Carbon Fiber Composites Innovation Research Institute Co., Ltd., Shanghai 201602, China;
    4. Shanghai Collaborative Innovation Center for High Performance Fiber Composites, Donghua University, Shanghai 201620, China
  • Received:2022-05-05 Online:2023-06-28 Published:2023-08-22

Abstract: In order to improve the interfacial properties of carbon fiber reinforced polyamide 6(CF/PA6) composites, the CF/PA6 composites were prepared by vacuum molding process using copolyamide water-based sizing agent as surface modifier. The microstructure, elemental changes and mechanical properties of CF and CF/PA6 composites were characterized by scanning electron microscopy, X-ray photoelectron spectroscopy and universal testing machine. The experimental results show that the sizing process can successfully connect the copolyamide to the surface of carbon fiber and improve the binding ability between carbon fiber and polyamide 6. When the concentration of copolyamide waterborne sizing agent is 0.5%, the mechanical properties of CF/PA6 composite is the best. The bending strength and interlaminar shear strength of CF/PA6 composite are 1044.5 MPa and 70.6 MPa, which are increased by 64.4% and 97.8% respectively, compared with those without treatment.

Key words: carbon fiber, polyamide 6, sizing agent, surface modification, mechanical property, composites

CLC Number: