纳米ZnO树脂薄膜提升CFRP层合板层间断裂性能研究

doi:10.19936/j.cnki.2096-8000.20250428.009

复合材料科学与工程 ›› 2025, Vol. 0 ›› Issue (4): 74-81.DOI: 10.19936/j.cnki.2096-8000.20250428.009

纳米ZnO树脂薄膜提升CFRP层合板层间断裂性能研究

杜徐玮^1,2, 牛雪娟^1,2*

1.天津工业大学机械工程学院,天津 300387;
2.天津市现代机电装备技术重点实验室,天津 300387

收稿日期:2024-02-06 出版日期:2025-04-28 发布日期:2025-06-03
通讯作者: 牛雪娟(1977—),女,博士研究生,教授,主要从事复合材料成型技术方面的研究,niuxuejuan@tiangong.edu.cn。
作者简介:杜徐玮(1998—),男,硕士研究生,主要从事碳纤维复合材料薄膜增韧方面的研究。
基金资助:
仿生多相共固微构型CFRP的可控合成及热压固化特性研究(23JCZDJC00450)

Research on improving the interlayer fracture performance of CFRP laminates with nano ZnO resin films

DU Xuwei^1,2, NIU Xuejuan^1,2*

1. School of Mechanical Engineering, Tiangong University, Tianjin 300387, China;
2. Advanced Mechatronics Equipment Technology Tianjin Area Major Laboratory, Tianjin 300387, China

Received:2024-02-06 Online:2025-04-28 Published:2025-06-03

摘要/Abstract

摘要： 碳纤维/聚合物基复合材料(CFRP)层合板法向刚度远低于面内刚度,当受到面外载荷作用时,极易发生损伤失稳。为了对厚度方向进行增韧,研究了改性纳米ZnO增韧薄膜对CFRP层合板力学性能的影响。首先使用偶联剂对纳米ZnO进行改性,得到改性后的纳米ZnO,将不同质量分数(0~4wt%)的改性纳米ZnO颗粒在固化剂的作用下混合加入环氧树脂中,在复合材料试件的两个界面之间形成了具有不同层间性能的黏结膜,并将其应用于端部缺口弯曲(ENF)试验和双悬臂梁(DCB)试验。建立了一系列有限元模型,并结合试验数据确定的模型参数对改性纳米ZnO和固化剂的影响进行了分析。结果表明,对于增韧梁(含4wt%改性纳米ZnO和2wt%GEL2-BS),ENF试验和DCB试验的临界载荷分别增加了30.25%和68.40%。

关键词: 黏结膜, 改性纳米ZnO颗粒, 界面增韧, 端部缺口弯曲试验, 双悬臂梁试验

Abstract: Carbon fiber reinforced plastics (CFRP) laminates are prone to damage and instability when subjected to out of plane loads due to their significantly lower normal stiffness compared to in-plane stiffness. In order to toughen the thickness direction, the effect of modified nano ZnO toughened films on the mechanical properties of CFRP laminates was studied. Nano-ZnO is first modified by coupling agent to obtain modified nano-ZnO, which was added into epoxy resin as nano-filler. By blending modified nano-ZnO particles at different mass ratios from 0 to 4wt% in the presence of a curing agent, some cohesive films with different interlaminar properties were formed between the two interfacial surfaces in a composite specimen, which have been applied in end-notched flexure (ENF) tests and double cantilever beam (DCB) tests. A series of finite element (FE) models, together with the predetermined model parameters, were built to assess the influence of modified nano-ZnO and curing agent. The results show that, for the toughened beam (with 4wt% modified nano-ZnO and 2wt% GEL2-BS), the critical loads of ENF tests and DCB tests increases by 30.25% and 68.40%, respectively.

Key words: cohesive film, modified nano-ZnO particles, interface toughening, end-notched flexure (ENF) tests, double cantilever beam (DCB) tests

中图分类号:

TB332

杜徐玮, 牛雪娟. 纳米ZnO树脂薄膜提升CFRP层合板层间断裂性能研究[J]. 复合材料科学与工程, 2025, 0(4): 74-81.

DU Xuwei, NIU Xuejuan. Research on improving the interlayer fracture performance of CFRP laminates with nano ZnO resin films[J]. COMPOSITES SCIENCE AND ENGINEERING, 2025, 0(4): 74-81.

参考文献

[1] 杨广林, 张启青, 史宾, 等. 碳纤维复合材料在汽车上的应用及成型工艺进展. 塑料工业, 2023, 51(11): 27-33.
[2] 赵丽滨, 龚愉, 张建宇. 纤维增强复合材料层合板分层扩展行为研究进展. 航空学报, 2019, 40(1): 171-199.
[3] 王慧, 王秀玲, 丁著明. 无机纳米粒子在环氧树脂增韧改性中的应用. 热固性树脂, 2018, 33(6): 55-65.
[4] 代少伟, 周玉敬, 李伟东, 等. 氧化石墨烯-碳纳米管复合膜层间增韧碳纤维/环氧树脂复合材料. 复合材料学报, 2023, 40(7): 1-11.
[5] 龙凌吟, 朱俊, 张丹暇, 等. 碳化硅晶须增强复合材料性能研究进展. 功能材料, 2023, 54(11): 11091-11098.
[6] 朱德智. 增强增韧的环氧树脂/二氧化硅纳米复合材料的制备与研究. 塑料工业, 2017, 45(6): 66-69.
[7] DATTA J, WŁOCH M. Influence of selected submicron inorganic particles on mechanical and thermo-mechanical properties of unsaturated polyester/glass composites. Journal of Reinforced Plastics and Composites, 2014, 33(10): 935-941.
[8] TORRES M, RODRIGUEZ V R, ALCANTARA P I, et al. Mechanical properties and fracture behaviour of agave fibers bio-based epoxy laminates reinforced with zinc oxide. Journal of Industrial Textiles, 2020, 51(4): 5847S-5868S.
[9] JIANG Y, WU J. Enhancement of interface strength of carbon fiber/epoxy resin composites filled with low-dimensional materials. Composite Interfaces, 2020, 28(3): 273-286.
[10] LIN Y, EHLERT G, SODANO H A. Increased interface strength in carbon fiber composites through a ZnO nanowire interphase. Advanced Functional Materials, 2009, 19(16): 2654-2660.
[11] 范雨娇, 顾轶卓, 邓火英, 等. 碳纳米管加入方式对碳纤维/环氧树脂复合材料层间性能的影响. 复合材料学报, 2015, 32(2): 332-340.
[12] CHEN Z, LUO J, HUANG Z, et al. Synergistic toughen epoxy resin by incorporation of polyetherimide and amino groups grafted MWCNTs. Composites Communications, 2020, 21(8): 100377.
[13] YUN N G, WON Y G, KIM S C. Toughening of carbon fiber/epoxy composite by inserting polysulfone film to form morphology spectrum. Polymer, 2004, 45(20): 6953-6958.
[14] ZHU L. Investigations on damage resistance of carbon fiber composite panels toughened using veils. Chinese Journal of Aeronautics, 2013, 26(3): 807-813.
[15] 刘志真, 郭恩玉, 邢军, 等. “离位”增韧技术在碳纤维/RTM聚酰亚胺复合材料中的应用. 复合材料学报, 2010, 27(6): 1-8.
[16] 李英梅, 刘军, 黄宝宗. 短纤维夹层对Ⅰ型层间断裂韧性的影响. 东北大学学报(自然科学版), 2002, 23(11): 1119-1122.
[17] RAMI K Z, KIM Y-R, KHEDMATI M, et al. Two-way linked multiscale method integrated with nanomechanical tests and cohesive zone fracture to model highly heterogeneous binding materials. Journal of Engineering Mechanics, 2018, 144(10): 04018095.
[18] 张凤鹏, 刘海, 黄宝宗. 冲击载荷作用下层间短纤维增韧研究. 东北大学学报(自然科学版), 2007, 28(4): 605-608.
[19] 姚佳伟, 张腾, 牛一凡. 非连续湿热作用下树脂基复合材料性能变化及机理的研究. 塑料工业, 2017, 45(12): 83-86.
[20] 张金童, 杨涛, 杜宇, 等. 超声振动对手糊成型碳纤维复合材料力学性能的影响. 复合材料科学与工程, 2023(10): 87-93.
[21] HU C X, HUANG G B, LI C. Experimental and numerical study of low-velocity impact and tensile after impact for CFRP laminates single-lap joints adhesively bonded structure. Materials, 2021, 14(4): 1016.
[22] 邢文涛, 孙会来, 李航, 等. 螺旋铣磨碳纤维复合材料铣磨力仿真及试验研究. 复合材料科学与工程, 2023(9): 85-91.

纳米ZnO树脂薄膜提升CFRP层合板层间断裂性能研究

Research on improving the interlayer fracture performance of CFRP laminates with nano ZnO resin films

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 1

编辑推荐

Metrics

本文评价