SiCf/SiC复合材料:SiC纤维、制备技术及其在航空发动机的应用进展

doi:10.19936/j.cnki.2096-8000.20251228.017

摘要/Abstract

摘要： SiC_f/SiC复合材料具有轻质低密度、优异的高温稳定性、良好的机械性能、突出的化学稳定性和高耐磨损特性,是航空发动机热端部件的理想材料。本文主要介绍SiC纤维的发展现状、SiC_f/SiC复合材料的制备工艺及其性能、SiC_f/SiC复合材料在航空发动机的应用进展,分析了当前SiC_f/SiC复合材料发展面临的挑战,提出SiC_f/SiC复合材料进一步发展的重点。

关键词: SiC_f/SiC复合材料, SiC纤维, 制备工艺, 航空发动机应用

Abstract: SiC_f/SiC composite materials exhibit characteristics such as lightweight, low density, excellent high-temperature stability, superior mechanical properties, outstanding chemical stability, and high wear resistance, making them ideal for hot-section components in aero-engines. This paper primarily introduces the current development status of SiC fibers, the fabrication processes and properties of SiC_f/SiC composites, and the application progress of SiC_f/SiC composites in aero-engines. It further analyzes the challenges currently faced in the development of SiC_f/SiC composites and proposes key priorities for their future advancement.

Key words: SiC_f/SiC composite materials, SiC fibers, preparation techniques, application in aero-engines

中图分类号:

TB332

焦春荣, 焦健. SiC_f/SiC复合材料:SiC纤维、制备技术及其在航空发动机的应用进展[J]. 复合材料科学与工程, 2025, 0(12): 131-137.

JIAO Chunrong, JIAO Jian. SiC_f/SiC composite materials:SiC fibers, preparation techniques and application progress in aero-engines[J]. COMPOSITES SCIENCE AND ENGINEERING, 2025, 0(12): 131-137.

参考文献

[1] 李世波, 徐永东, 张立同. 碳化硅纤维增强陶瓷基复合材料的研究进展[J]. 材料导报, 2001, 15(1): 45-49.
[2] LIU Q M, HUANG S Z, HE A J. Application requirements and challenges of CMC-SiC composites on aero-engine[J]. Journal of Materials Engineering, 2019, 47(2): 1-10.
[3] YIN X W, CHENG L F, ZHANG L T, et al. Fibre-reinforced multifunctional SiC matrix composite materials[J]. International Materials Reviews, 2017, 62(3): 117-172.
[4] 李伟, 许志明, 苟燕子, 等. SiC纤维烧结陶瓷的制备及性能研究[J]. 无机材料学报, 2025, 40(2): 177-183.
[5] XIANG Y, WU S, YU J S, et al. Long-time oxidation behavior of the nearly stoichiometric polycrystalline SiC fibers under air atmosphere at different temperatures[J]. Journal of the European Ceramic Society, 2024, 44(6): 3569-3578.
[6] MIAO Z S, HUANG J, WANG X Y, et al. Oxygen evolution in the organic-inorganic transformation of polycarbosilane fibers via temperature-programmed analysis[J]. Journal of the American Ceramic Society, 2025, 108(9): 20600.
[7] CHEN J, ZHAO Z Q, HE Y T, et al. Formation mechanism of graphite or graphene fibers with core-shell structure from nearly stoichiometric polycrystalline SiC fibers[J]. Materials Characterization, 2025, 23(2): 173-179.
[8] ZHAO Z Q, LIAO W, CHEN J, et al. Advanced research on the preparation and application of carbide ceramic fibers[J]. Journal of Advanced Ceramics, 2024, 13(9): 1291-1336.
[9] MONDAL M I H. Technical organic and inorganic fibres from natural resources[M]. Cambridge: Woodhead Publishing, Elsevier Science Ltd., 2025: 527-555.
[10] REBILLAT F, GUETTE A, ESPITALIER L. Chemical and mechanical degradation of Hi-Nicalon and Hi-Nicalon-S fibers under CVD/CVI BN processing conditions[J]. Key Engineering Materials, 1999, 164/165: 31-34.
[11] MORIMOTO T, OGASAWARA T. Potential strength of Nicalon^TM, Hi Nicalon^TM, and Hi Nicalon Type S^TM monofilaments of variable diameters[J]. Composites Part A: Applied Science and Manufacturing, 2006, 37(3): 405-412.
[12] CHU Z-Y, FENG C-X, SONG Y-C. Development of a new Si-C-O-N-B ceramic fiber using a hybrid precursor of polycarbosilane and polyborosilazane[J]. Journal of Materials Science Letters, 2003, 22(10): 725-728.
[13] TAKEDA M, URANO A, SAKAMOTO J, et al. Microstructure and oxidative degradation behavior of silicon carbide fiber Hi-Nicalon type S[J]. Journal of Nuclear Materials, 1998, 258: 1594-1599.
[14] SHIMODA K, COLIN C. Thermo-physical, -mechanical, and -electrical behaviors of ion-irradiated Tyranno-SA SiC fibers at high temperatures (1 473 K)[J]. Journal of Nuclear Materials, 2013, 442(1): 376-379.
[15] PATEL M, SAURABH K, PRASAD V V B, et al. High temperature C/C-SiC composite by liquid silicon infiltration: a literature review[J]. Bulletin of Materials Science, 2012, 35(1): 63-73.
[16] 刘虎, 杨金华, 焦健. 航空发动机用连续SiC_f/SiC复合材料制备工艺及应用前景[J]. 航空制造技术, 2017(16): 90-95.
[17] AMIRTHAN G, UDAYAKUMAR A, PRASAD V V B, et al. Properties of Si/SiC ceramic composite subjected to chemical vapour infiltration[J]. Ceramics International, 2009, 35(7): 2601-2607.
[18] TIMMS L A, WESTBY W, PRENTICE C, et al. Reducing chemical vapour infiltration time for ceramic matrix composites[J]. Journal of Microscopy, 2010, 201(2): 316-323.
[19] WEI Y C, YE F, ZHANG Y, et al. Ultrahigh room and high-temperature mechanical properties of SiCf/SiC composites prepared by hybrid CVI and PIP methods: effects of PIP temperature[J]. Composites Part A: Applied Science and Manufacturing, 2025, 188: 108502.
[20] 沈轩逸, 马沁, 薛玉冬, 等. 复合界面层对SiC_f/SiC复合材料力学损伤行为的影响[J]. 无机材料学报, 2023, 38(8): 917-922.
[21] QIN Y M, ZHENG C, LI X Q. The corrosion behavior of CVD SiC coatings on SiC_f/SiC composites in a simulated molten salt reactors environment[J]. Corrosion Science, 2022, 204: 110411.
[22] 刘桂良, 何宗倍, 王梓璇, 等. CVD工艺参数对SiC涂层结晶度与耐腐蚀性的定量研究[J]. 复合材料科学与工程, 2021(3): 71-77.
[23] 赵日达, 汤素芳. 多孔碳陶瓷化改进反应熔渗法制备陶瓷基复合材料研究进展[J]. 无机材料学报, 2024, 39(6): 623-633.
[24] 刘虎, 杨金华, 陈子木, 等. 熔融渗硅工艺制备的SiC_f/SiC复合材料微观结构与性能[J]. 宇航材料工艺, 2020, 50(6): 48-54.
[25] LANGE F F, TU W C, EVANS A G. Processing of damage-tolerant, oxidation-resistant ceramic matrix composites by a precursor infiltration and pyrolysis method[J]. Materials Science & Engineering: A, 1995, 195: 145-150.
[26] HE R J, DING G J, ZHANG K Q, et al. Fabrication of SiC ceramic architectures using stereolithography combined with precursor infiltration and pyrolysis[J]. Ceramics International, 2019, 45(11): 14006-14014.
[27] 中国人民解放军国防科技大学. 一种高导热SiC_f/SiC复合材料及其制备方法: CN202410237859.8[P]. 2024-05-28.
[28] 杨金华, 姜卓钰, 吕晓旭, 等. 熔融渗硅处理对PIP工艺制备的SiC_f/SiC复合材料性能影响[J]. 陶瓷学报, 2019, 40(6): 833-839.
[29] ZHAO H, CHEN L X, LUAN X G, et al. Synthesis, pyrolysis of a novel liquid SiBCN ceramic precursor and its application in ceramic matrix composites[J]. Journal of the European Ceramic Society, 2017, 37(4): 1321-1329.
[30] KIM K M, HAHN Y, LEE S M, et al. Mechanical properties of C_f/SiC composite using a combined process of chemical vapor infiltration and precursor infiltration pyrolysis[J]. Journal of the Korean Ceramic Society, 2018, 55(4): 392-399.
[31] 姜卓钰, 吕晓旭, 周怡然, 等. PIP工艺制备SiC晶须增强SiC_f/SiC复合材料的性能[J]. 航空材料学报, 2021, 41(2): 82-88.
[32] 刘海韬, 程海峰, 王军, 等. PIP工艺制备2D-SiC_f/SiC复合材料力学性能影响研究[J]. 稀有金属材料与工程, 2008(10): 87-89.
[33] 梁艳媛, 刘青铜, 邱海鹏, 等. 氧化铝料浆预浸料结合PIP工艺制备SiC/Al₂O₃-SiC陶瓷基复合材料及性能研究[J]. 现代技术陶瓷, 2023, 44(增刊1): 423-430.
[34] SHIMODA K, PARK J S, HINOKI T, et al. Influence of pyrolytic carbon interface thickness on microstructure and mechanical properties of SiC/SiC composites by NITE process[J]. Composites Science and Technology, 2008, 68(1): 98-105.
[35] SHIMODA K, KOHYAMA A, HINOKI T. High mechanical performance SiC/SiC composites by NITE process with tailoring of appropriate fabrication temperature to fiber volume fraction[J]. Composites Science and Technology, 2009, 69(10): 1623-1628.
[36] 焦健, 赵文青, 齐哲, 等. BN和BN/SiC涂层对SiC纤维单丝拉伸性能的影响及其失效行为[J]. 材料工程, 2023, 51(2): 152-159.
[37] YU H J, ZHOU X G, ZHANG W, et al. Mechanical behavior of SiC_f/SiC composites with alternating PyC/SiC multilayer interphases[J]. Materials & Design, 2013, 44: 320-324.
[38] CUI G Y, LUO R Y, WANG L Y, et al. Mechanical properties evolution of SiC_f/SiC composites with a BN/SiC multilayer interface oxidized at elevated temperature[J]. Applied Surface Science, 2021, 570: 151065.
[39] LUE X X, LI L B, SUN J J, et al. Microstructure and tensile behavior of (BN/SiC)_n coated SiC fibers and SiC/SiC minicomposites[J]. Journal of the European Ceramic Society, 2023, 43(5): 1828-1842.
[40] 李明远. SiCf/SiC复合材料的性能研究及仿真计算[D]. 长沙: 国防科技大学, 2019.
[41] CHRISTIN F. Design, fabrication, and application of thermostructural composites (TSC) like C/C, C/SiC, and SiC/SiC composites[J]. Advanced Engineering Materials, 2002, 4(12): 903-912.
[42] CHRISTIN F. A global approach to fiber nD architectures and self-sealing matrices: from research to production[J]. International Journal of Applied Ceramic Technology, 2005, 2(2): 97-104.
[43] 刘巧沐, 黄顺洲, 何爱杰. 碳化硅陶瓷基复合材料在航空发动机上的应用需求及挑战[J]. 材料工程, 2019, 47(2): 1-10.
[44] CORMAN G, LUTHRA K. Development history of GE’s prepreg melt infiltrated ceramic matrix composite material and applications[M]. Netherlands: Elsevier, 2017.
[45] KATOH Y, SNEAD L L, HENAGER C H, et al. Current status and recent research achievements in SiC/SiC composites[J]. Journal of Nuclear Materials, 2014, 455(1): 387-397.
[46] 张岩, 戴淑波. GE的陶瓷基复合材料发展概述[J]. 航空动力, 2019(3): 62-64.
[47] 王雅娜, 李天山, 王海润, 等. GE公司预浸料-熔渗工艺SiC_f/SiC复合材料应用研究历程及启示[J]. 航空材料学报, 2025, 45(2): 1-17.
[48] 焦健, 孙世杰, 焦春荣, 等. SiC_f/SiC复合材料涡轮导向叶片研究进展[J]. 复合材料学报, 2023, 40(8): 4342-4354.
[49] BHATIA T, JARMON D, SHI J, et al. CMC combustor liner demonstration in a small helicopter engine[C]//ASME. ASME Turbo Expo 2010: Power for Land, Sea, and Air. Glasgow, UK: ASME, 2010: 509-513.
[50] 袁钦, 宋永才. 连续SiC纤维和SiCf/SiC复合材料的研究进展[J]. 无机材料学报, 2016, 31(11): 1157-1165.
[51] 刘宝林, 刘荣军, 张长瑞, 等. SiC_f/SiC复合材料高温抗氧化研究进展[J]. 硅酸盐通报, 2014, 33(5): 1107-1118.