联苯型环氧树脂强韧化TDE-85树脂体系的制备与性能

doi:10.19936/j.cnki.2096-8000.20241228.006

复合材料科学与工程 ›› 2024, Vol. 0 ›› Issue (12): 43-48.DOI: 10.19936/j.cnki.2096-8000.20241228.006

联苯型环氧树脂强韧化TDE-85树脂体系的制备与性能

侯镇弘¹, 陆奇², 赵星诺¹, 徐锦文¹, 夏宏伟³, 张颂³, 侯锐钢¹, 周权^1*

1.华东理工大学材料科学与工程学院特种功能高分子材料及相关技术教育部重点实验室,上海 200237;
2.浙江晨诺高分子材料有限公司,嘉兴 314204;
3.无锡新宏泰电器科技股份有限公司, 无锡 214174

收稿日期:2024-04-18 出版日期:2024-12-28 发布日期:2025-01-14
通讯作者: 周权(1973—),男,博士,教授,博士生导师,研究方向为高性能基体树脂及其复合材料,qzhou@ecust.edu.cn。
作者简介:侯镇弘(1999—),男,硕士,研究方向为环氧树脂的改性。
基金资助:
中央高校基本科研业务费专项资金(JKD01231701)

Preparation and properties of TDE-85 resin system strengthened and toughened by biphenyl epoxy resin

HOU Zhenhong¹, LU Qi², ZHAO Xingnuo¹, XU Jinwen¹, XIA Hongwei³, ZHANG Song³, HOU Ruigang¹, ZHOU Quan^1*

1. Key Laboratory of Specially Functional Polymeric Materials and Related Technology of Ministry of Education, School of Material Science and Engineering, Shanghai 200237, China;
2. Zhejiang Chennuo Polymer Materials Co., Ltd., Jiaxing 314204, China;
3. Wuxi New Hongtai Electrical Technology Co., Ltd., Wuxi 214174, China

Received:2024-04-18 Online:2024-12-28 Published:2025-01-14

摘要/Abstract

摘要： 环氧树脂因其黏结力强、热稳定性好等优点,被广泛应用于涂料、电子封装材料和胶黏剂等领域,但其高交联密度也带来了脆性大、韧性差的问题,成为制约其发展应用的主要因素。采用熔融共混的方法,以3,3′-二氨基二苯砜(3,3′-DDS)为固化剂,用联苯型环氧树脂3,3′,5,5′-四甲基联苯双酚二缩水甘油醚(TMBP)改性高性能环氧树脂(TDE-85)。研究了改性树脂体系的力学性能,偏光显微镜和扫描电子显微镜的分析表明液晶结构能良好分散在环氧树脂基体中并增强增韧。结果表明:当TMBP含量为6wt％时,固化物的力学性能明显提高,冲击强度和弯曲强度分别提高了30%和27%,韧性和强度明显提升;当TMBP含量为4wt%时,拉伸强度和拉伸模量均达到最大,分别为93.69 MPa与5.39 GPa。

关键词: 环氧树脂, 热性能, 力学性能, 共混改性, 液晶结构, 复合材料

Abstract: Epoxy resin is widely used in coatings, electronic packaging materials and adhesives because of its strong adhesive strength and good thermal stability, but its high cross-linking density also brings the problem of brittleness and poor toughness, which has become the main factor restricting its development and application. A high performance epoxy resin (TDE-85) was modified by biphenyl epoxy resin 3,3′,5,5′ -tetramethylbiphenyl bisphenol diglycidyl ether (TMBP) with 3,3′ -diaminodiphenyl sulfone (3,3′-DDS) as curing agent by melt blending method. The mechanical properties of the modified resin system were studied. The results of polarizing microscope and SEM showed that the liquid crystal structure could be well dispersed in the epoxy resin matrix and strengthened and toughened. The results show that when the TMBP content is 6wt%, the mechanical properties of the cured material are obviously improved, the impact strength and flexural strength are increased by 30% and 27% respectively, and the strength and toughness is obviously improved. When the TMBP content is 4wt%, the tensile strength and tensile modulus reach the maximum of 93.69 MPa and 5.39 GPa.

Key words: epoxy resin, thermal properties, mechanical properties, blending modification, liquid crystal structure, composites

中图分类号:

TB332

侯镇弘, 陆奇, 赵星诺, 徐锦文, 夏宏伟, 张颂, 侯锐钢, 周权. 联苯型环氧树脂强韧化TDE-85树脂体系的制备与性能[J]. 复合材料科学与工程, 2024, 0(12): 43-48.

HOU Zhenhong, LU Qi, ZHAO Xingnuo, XU Jinwen, XIA Hongwei, ZHANG Song, HOU Ruigang, ZHOU Quan. Preparation and properties of TDE-85 resin system strengthened and toughened by biphenyl epoxy resin[J]. COMPOSITES SCIENCE AND ENGINEERING, 2024, 0(12): 43-48.

参考文献

[1] GUO W W, WANG X, GANGIREDDY C S R, et al. Cardanol derived benzoxazine in combination with boron-doped graphene toward simultaneously improved toughening and flame retardant epoxy composites[J]. Composites Part A: Applied Science and Manufacturing, 2019, 116: 13-23.
[2] RICO M, LÓPEZ J, MONTERO B, et al. Phase separation and morphology development in a thermoplastic-modified toughened epoxy[J]. European Polymer Journal, 2012, 48(10): 1660-1673.
[3] DENG S Q, DJUKIC L, PATON R, et al. Thermoplastic-epoxy interactions and their potential applications in joining composite structures-A review[J]. Composites Part A: Applied Science and Manufacturing, 2015, 68: 121-132.
[4] CHEN S F, XU Z J, ZHANG D H. Synthesis and application of epoxy-ended hyperbranched polymers[J]. Chemical Engineering Journal, 2018, 343: 283-302.
[5] RICCIARDI M R, PAPA I, LANGELLA A, et al. Mechanical properties of glass fibre composites based on nitrile rubber toughened modified epoxy resin[J]. Composites Part B: Engineering, 2018, 139: 259-267.
[6] XU C, QU T G, ZHANG X J, et al. Enhanced toughness and thermal conductivity for epoxy resin with a core-shell structured polyacrylic modifier and modified boron nitride[J]. RSC advances, 2019, 9(15): 8654-8663.
[7] DHEVI D M, JAISANKAR S N, PATHAK M. Effect of new hyperbranched polyester of varying generations on toughening of epoxy resin through interpenetrating polymer networks using urethane linkages[J]. European Polymer Journal, 2013, 49(11): 3561-3572.
[8] ROSSO P, YE L, FRIEDRICH K, et al. A toughened epoxy resin by silica nanoparticle reinforcement[J]. Journal of Applied Polymer Science, 2006, 100(3): 1849-1855.
[9] CHEN C G, JUSTICE R S, SCHAEFER D W, et al. Highly dispersed nanosilica-epoxy resins with enhanced mechanical properties[J]. Polymer, 2008, 49(17): 3805-3815.
[10] MA J, MO M S, DU X S, et al. Effect of inorganic nanoparticles on mechanical property, fracture toughness and toughening mechanism of two epoxy systems[J]. Polymer, 2008, 49(16): 3510-3523.
[11] JAJAM K C, RAHMAN M M, HOSUR M V, et al. Fracture behavior of epoxy nanocomposites modified with polyol diluent and amino-functionalized multi-walled carbon nanotubes: a loading rate study[J]. Composites Part A: Applied Science and Manufacturing, 2014, 59: 57-69.
[12] ASIF A A, JOHN B, RAO V L, et al. Surface morphology, thermomechanical and barrier properties of poly(ether sulfone)-toughened epoxy clay ternary nanocomposites[J]. Polymer International, 2010, 59(7): 986-997.
[13] THOMAS R, DING Y M, HE Y L, et al. Miscibility, morphology, thermal, and mechanical properties of a DGEBA based epoxy resin toughened with a liquid rubber[J]. Polymer, 2008, 49(1): 278-294.
[14] TANG Y H, XUE G, ZHANG B, et al. Epoxidized natural rubber based core-shell particles-synthesize, characterization and toughening studies[J]. Journal of Polymer Materials, 2015, 32(3): 271-284.
[15] SIDDHAMALLI S K, KYU T. Toughening of thermoset/thermoplastic composites via reaction-induced phase separation: epoxy/phenoxy blends[J]. Journal of Applied Polymer Science, 2000, 77(6): 1257-1268.
[16] 苏江. 液晶环氧树脂的研究进展[J]. 热固性树脂, 2016, 31(1): 56-62.
[17] 张新超, 王小慕, 马嘉浩, 等. 沉淀法合成联苯基液晶环氧及强韧化体系的制备[J]. 精细化工, 2023, 40(1): 214-223, 232.
[18] 孙曼灵. 环氧树脂应用原理与技术[M]. 北京: 机械工业出版社, 2002.
[19] 汪瀚湘. 联苯型液晶改性环氧树脂中氮化硼取向导热网络构建方法[D]. 重庆: 重庆大学, 2020.

联苯型环氧树脂强韧化TDE-85树脂体系的制备与性能

Preparation and properties of TDE-85 resin system strengthened and toughened by biphenyl epoxy resin

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	张茜, 张一帆, 邹齐, 张鹏, 焦亚男, 安柳絮, 刘燕峰, 张代军, 郝俊杰, 陈利. 三维机织复合材料的连接性能与失效机制[J]. 复合材料科学与工程, 2024, 0(9): 5-11.
[2]	燕吉强, 谢宗佑, 李军, 邹齐, 雷帅, 曹铁男, 张代军. 铺层角度对聚酰亚胺纤维增强复合材料抗高速冲击性能影响[J]. 复合材料科学与工程, 2024, 0(9): 12-18.
[3]	吕续津, 霍红宇, 彭公秋, 张宝艳, 叶金秋, 刘勇. 静电纺丝PPESK纤维毡层间增韧碳纤维/环氧树脂复合材料[J]. 复合材料科学与工程, 2024, 0(9): 19-27.
[4]	郭妙才. 导电颗粒改性高韧性复合材料的层间结构和雷击损伤特性[J]. 复合材料科学与工程, 2024, 0(9): 28-36.
[5]	李沫莹, 郑林峰, 刘刚, 李梦娇, 姚佳楠. 碳纤维/聚芳醚酮热塑性复合材料与环氧涂层的附着力研究[J]. 复合材料科学与工程, 2024, 0(9): 37-42.
[6]	谢文博. 耐高温阻燃环氧树脂碳纤维复合材料性能研究[J]. 复合材料科学与工程, 2024, 0(9): 43-47.
[7]	黄大明, 唐立鑫, 孙军涛, 王炜. 残留单体丙烯腈对PAN基碳纤维制备的影响研究[J]. 复合材料科学与工程, 2024, 0(9): 48-51.
[8]	冯振辉, 王哲, 曾捷, 陈斌斌, 冯春乐, 周帆. 复合材料层板光纤冲击判位与载荷历程重构方法[J]. 复合材料科学与工程, 2024, 0(9): 52-56.
[9]	张德伟, 卫炜, 张聘, 王琦, 赵聪, 安鲁陵. 基于实测数据的飞机复合材料构件外形调控[J]. 复合材料科学与工程, 2024, 0(9): 57-66.
[10]	闫超, 戎笑远, 赵月青, 钱忠健. 复合材料共胶接帽形长桁加筋壁板的固化变形研究[J]. 复合材料科学与工程, 2024, 0(9): 67-72.
[11]	闫磊, 赵飞, 还大军, 张盛源, 王斌, 肖军. T700/PPS热塑缠绕复合材料NOL环拉-拉疲劳行为研究及寿命预测初探[J]. 复合材料科学与工程, 2024, 0(9): 73-81.
[12]	成李冰, 徐伟伟, 李博, 文诗琦. 复合材料肋零件微波固化成型工艺研究[J]. 复合材料科学与工程, 2024, 0(9): 82-86.
[13]	武海生, 罗锦涛, 顾轶卓, 孙天峰, 刘佳, 姚旗, 黎昱. 高模量碳纤维复合材料管件高低温交变环境结构稳定性研究[J]. 复合材料科学与工程, 2024, 0(9): 87-91.
[14]	付成建, 林松, 郭淑芬. 基于渐进损伤的Ⅳ型复合材料气瓶的爆破压强预测分析[J]. 复合材料科学与工程, 2024, 0(9): 92-97.
[15]	徐林, 刘传军, 赵崇书. 复合材料在民用飞机应用与发展趋势[J]. 复合材料科学与工程, 2024, 0(9): 98-104.