复合材料科学与工程 ›› 2014, Vol. 0 ›› Issue (4): 23-26.

• 基础研究 • 上一篇    下一篇

Vectran纤维的耐热稳定性研究

杜以军1, 蒋金华1,2, 陈南梁1,2,3*   

  1. 1.东华大学纺织学院,上海201620;
    2.产业用纺织品教育部工程研究中心,上海201620;
    3.东华大学研究院,上海201620
  • 收稿日期:2013-06-27 发布日期:2021-09-17
  • 通讯作者: 陈南梁,nlch@dhu.edu.cn。
  • 作者简介:杜以军(1987-),男,在读硕士研究生,主要从事产业用纺织品的研究和开发。
  • 基金资助:
    国家科技支撑计划(2011BAE10B00);中央高校基本科研业务费专项资金项目(13D110126)

RESEARCH ON HEAT RESISTANCE OF VECTRAN FIBER

DU Yi-jun1, JIANG Jin-hua1,2, CHEN Nan-liang1,2,3*   

  1. 1. College of Textiles, Donghua University, Shanghai 201620, China;
    2. Engineering Research Center of Technical Textiles, Ministry of Education, Shanghai 201620, China;
    3. Institute of Donghua University, Shanghai 201620, China
  • Received:2013-06-27 Published:2021-09-17

摘要: 为了解Vectran纤维的耐热稳定性,使用烘箱对其进行了热老化处理,测试了其拉伸性能、失重率,并利用SEM、红外分析、DSC手段研究了试样外观以及分子结构受热老化的影响。结果表明,Vectran纤维的耐热性能较好,从250℃开始,其强力开始快速下降;SEM表明Vectran纤维受热老化后表面产生纵条,温度越高,纵条越深,最终产生类似劈裂的效果;红外分析表明纤维大分子链的侧基C=O的振动发生变化,主链中C-O有可能发生断裂;DSC表明热老化处理使Vectran纤维的熔点有少许提升,这主要是高温提供分子链末端运动的机会,使分子链进一步固相紧缩。

关键词: Vectran纤维, 热老化, 拉伸, SEM, 红外分析, DSC

Abstract: Vectran fiber was subjected to heat treatments at different temperature to find out its heat resistance. The impact of temperature on the fiber′s tensile property and weight loss was investigated. The surface and chemical structure of the fiber were studied. The result shows that the heat resistance of Vectran fiber is good. Its tensile strength starts decreasing at about 250℃. The SEM photos suggest that strips would appear on the surface of Vectran fiber after being treated, and the depth of the stripes would increase by the higher temperature; it can be seen from the ATR-FTIR spectra that 1725cm-1 and 1110cm-1 are weaken by the high temperature, which attribute to C=O and C-O. The DSC shows that Vectran′s melting-point raises a little because of heat treatment. The reason mightbe that the high temperature maycause the movement of the end of the molecular chain, which lead the molecular tighter and shorter.

Key words: vectran fiber, thermal aging, tensile property, SEM, ATR-FTIR, DSC

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